Aylward and Findlay's SI Chemical Data

ISBN-13: 9780730302469 / Angielski / Miękka / 2013 / 240 str.

Lawrie Gahan

Spis treści

About the authors iv
Preface iv
Acknowledgements v

Section 1: General: Physical constants, units and symbols
1 The International System of Units (SI) 3
2 SI derived units commonly used in chemistry 3
3 Fundamental constants (revised 2010) 4
4 Common conversion factors 4
5 The Greek alphabet 5
6 Numerical prefixes 5
7 Decimal fractions and multiples 6

Section 2: The elements
8 Ground state electronic configurations of the elements 9
9 Properties of the elements 14
10 Properties and applications of some common radioisotopes 22
11 Electronegativities of the elements (Pauling scale) 24
12 Enthalpies of melting, vaporisation and atomisation of the elements 25
13 First ionisation enthalpies (Ei1) of the elements 27
14 Successive ionisation enthalpies (Ein) of the elements 29
15 Electron affinities (Eea) of the elements 31

Section 3: Inorganic compounds
16 Properties of elements and inorganic compounds 35
17 Some crystal forms 84
18 Shapes of some molecules and ions 87
19 Bond lengths 88
20 Average bond enthalpies 89
21 Lattice enthalpies of ionic crystals 89
22 Stability constants of complex ions 90
23 Solubility products 91

Section 4: Organic compounds
24 Some important organic functional groups 95
25 Properties of organic compounds 97
26 Properties of amino acids 120
27 Properties of solvents 123
28 Miscibility of solvents 125
29 Boiling temperature elevation and freezing temperature depression constants 126
30 Critical constants and triple points 127

Section 5: Spectroscopic data
31 The spectral energies 131
32 Infrared absorption frequencies 131
33 NMR chemical shifts 132
34 Chemical shifts and multiplicities of residual protons in deuterated NMR solvents 132
35 NMR chemical shifts of common solvents in a variety of deuterated NMR solvents 133
36 Important NMR–active nuclei 137
37 Common singly charged (z = 1) fragments detected by mass spectrometry 137

Section 6: Properties of acids and bases
38 Dissociation constants of acids and hydrated metal ions 141
39 Aqueous concentrations of common acids 142
40 Common acid base indicators 143
41 Common buffers 143
42 Buffering ranges of some common biological buffers (0.1 m) 144

Section 7: Properties of aqueous solutions
43 Ionic properties of water 149
44 Molar conductivities of aqueous solutions at 298 K 149
45 Ionic molar conductivities at
infinite dilution at 298 K 149
46 Solubility of gases in water 150
47 Vapour pressure and density of water and mercury at different temperatures 150
48 Densities of aqueous solutions at 298 K 151

Section 8: Electrochemistry
49 Standard electrode potentials and redox equilibria in aqueous solution 155
50 Potentials of common reference electrodes at 298 K 159
51 Conversion factors (mV) between common reference electrodes in acetonitrile 160

Section 9: Appendices
52 Globally Harmonised System of Classification and Labelling of Chemicals (GHS) 163
53 Interpretation of a material safety data sheet (MSDS) 165
54 Common formulae and definitions 173

References 176
Index 181

O autorze

Allan Blackman is an Associate Professor of Chemistry in the Department of Chemistry, University of Otago, Dunedin, New Zealand. He has a PhD in Physical Inorganic Chemistry, and his research interests include coordination chemistry and chemical kinetics. He has 22 years experience in both teaching and research, is the co–author of a best–selling Australasian–focused first–year Chemistry textbook, and has won teaching awards at his home university. His monthly musings on things chemical can be found at http://neon.otago.ac.nz/chemistry/magazine/.

Lawrence R. Gahan is a Professor of Chemistry in the School of Chemistry and Molecular Biosciences, The University of Queensland, Australia. He has a PhD in Chemistry, has active research interests in bioinorganic chemistry, and has published extensively in international journals. Professor Gahan has 30 years experience in university teaching with various teaching and learning grants, and local and national awards for his teaching. In addition, he has been awarded competitive grants to support his chemistry research.

Blurb

SI Chemical Data, 7th edition, is a supplementary text for students in undergraduate chemistry courses and in high school subjects specialising in chemistry. The chemicals included have been chosen specifically to cover those typically studied in these courses.

New to this edition

The adoption of the Globally Harmonised System of Classification and Labelling of Chemicals (GHS) has necessitated extensive revision of the hazard codes that were elaborately detailed in earlier editions. Now, instead of listing individual hazard codes for each element and chemical, the GHS is explained in detail, along with how to interpret a material safety data sheet (MSDS). This information provides students with the skills to discover and understand the hazards that may be associated with the chemicals they use.

In addition to this major change, the order of the tables of data has been rearranged to systematise the sequence of presentation. The values of the fundamental constants have been updated, data have been updated based on the most recent published compendia and, in some cases, data have been presented in different formats to those in previous editions. New tables have been included to provide data and information on:

• common radioisotopes
• common amino acids
• the miscibility of common solvents
• 1H chemical shifts of residual protons in deuterated NMR solvents
• 1H and 13C chemical shifts of common solvents
• common biological buffers
• the potentials and conversion factors for common reference electrodes.