Part I Nucleation and Crystal Growth.- In-situ Solid-state NMR Studies of Crystallization Processes.- Structure of Supersaturated Solution and Crystal Nucleation.- Nucleation and Crystal Growth in Limited Crystallization Field.- Supersaturation-Sealed Protein Misfolding Funnels Revealed by Ultrasonication (Amyloid fibrillation).- Part II Structure and Morphology.- Supramolecular Chirality of Twofold Helical Columns in Organic Crystals.- Construction of Aromatic Folding Architecture.- Analysis of Intermolecular Interactions by ab initio Molecular Orbital Calculations.- Part III Polymorphism.- Polymorphism in Molecular Crystals and Cocrystals.- Hydration/Dehydration Phase Transition: Mechanism in Organic Crystals Investigated by ab initio Crystal Structure Determination from Powder Diffraction Data.- Polymorphism and Pseudopolymorhism in Organic Crystals.- Variety of Combinations of Weak Intermolecular Interactions in Crystal Polymorphs and Pseudopolymorphs.- Crystallization Tendency of Pharmaceutical Glasses.- Part IV Function.- Luminescence Modulation of Organic Crystal by Supramolecular Approach.- Azacalixarenes: Ever-Growing Versatile Macrocyclic Compounds.- Photoinduced Mechanical Motion of Photochromic Crystalline Materials.- Luminescent Crystal – Control of Luminescence Properties by the Mode of Molecular Packing.- Crystal Engineering Approach towards Molecule-Based Magnetic Materials.- Solid-state Circularly Polarized Luminescence of Chiral Supramolecular Organic Fluorophore.- Part V Chirality.- How to Use Pasteur’s Tweezers.- Chiral Discrimination in the Solid State and Applications to Resolution and Deracemization.- Total Resolution of Racemates by Dynamic Preferential Crystallization.- Preferential Enrichment:Origin and Application to Cocrystals.- Chiral Metal-Organic Framework Crystals.- Chiral Recognition by Inclusion Crystals of Amino Acid Derivatives.- Part VI Solid-State Polymerization.- Solid-State Polymerization for Structure Control.- Topochemical Polymerization of Amino Acid N-Carboxy Anhydrides in the Crystalline State.- Organic Layered Crystals for Multi-Component Organic Alloys and Topochemical Polymerization.
For the last decade, the topics of organic crystal chemistry have become diversified, and each topic has been substantially advanced in concert with the rapid development of various analytical and measurement techniques for solid-state organic materials. The aim of this book is to systematically summarize and record the recent notable advances in various topics of organic crystal chemistry involving liquid crystals and organic–inorganic hybrid materials that have been achieved mainly in the last 5 years or so. The authors are invited members of the Division of Organic Crystals, The Chemical Society of Japan (CSJ), and prominent invited experts from abroad. This edited volume is planned to be published periodically, at least every 5 years, with contributions by prominent authors in Japan and from abroad.