Advances in Chemistry Research. Volume 51

ISBN-13: 9781536150636 / Angielski

James C. Taylor

Opis

In this compilation, the authors begin by highlighting the recent developments in asymmetric 1,4- and 1,2- additions to , ss-unsaturated carbonyl compounds. The recent finding of Cu (I)-catalyzed asymmetric 1,2-addition of Grignard reagents to , ss-unsaturated carbonyl compounds, as well as aromatic ketones, has categorically revolutionized catalytic asymmetric reactions.This compilation also aims to use the well-known coordination preference of zinc in phthalocyanine and porphyrin ligands in correlation with supramolecular systems. The light-absorption process in dye-sensitized solar cells is studied using the time-dependent density functional theory.In recent years, a series of investigations on detonation wave formation in acetylene have been published. In these studies, it was shown that the formation of detonation proceeds entirely due to the energy released during the condensation of carbon nanoparticles during the growth of poly-aromatic hydrocarbons. The results of these studies are summarized and practical applications are discussed.The authors discuss aromatic amines, derivatives of aromatic hydrocarbons containing an amino group/an amine group/nitrogen atom in their structures. These compounds represent one of the most important classes of industrial and environmental chemicals. Three groups have been studied: monocyclic, polycyclic, and heterocyclic aromatic amines, which are used as intermediates in azo dye manufacturing, pigments, drugs, antibiotics, antidepressants, pesticides, and other industrial products.In the closing study, the GC-MS/MS method has been developed for the determination and quantification of 35 multiclass pesticide residues in chili samples. Pesticides were selected from different families including organochlorines, organophosphorus, carbamates, pyrethroids, triazines, triazoles, and pyrazoles. The QuEChERS-dSPE method was used for the extraction of pesticide residue.