Liquid-Liquid Interfacestheory and Methods: Theory and Methods

ISBN-13: 9780849376948 / Angielski / Twarda / 1996 / 448 str.

Volkov G. Volkov; Alexander Ed. Volkov; Alexander G. Volkov

Opis

Update your knowledge of the chemical, biological, and physical properties of liquid-liquid interfaces with Liquid-Liquid Interfaces: Theory and Methods. This valuable reference presents a broadly based account of current research in liquid-liquid interfaces and is ideal for researchers, teachers, and students. Internationally recognized investigators of electrochemical, biological, and photochemical effects in interfacial phenomena share their own research results and extensively review the results of others working in their area.
Because of its unusually wide breadth, this book has something for everyone interested in liquid-liquid interfaces. Topics include interfacial and phase transfer catalysis, electrochemistry and colloidal chemistry, ion and electron transport processes, molecular dynamics, electroanalysis, liquid membranes, emulsions, pharmacology, and artificial photosynthesis. Enlightening discussions explore biotechnological applications, such as drug delivery, separation and purification of nuclear waste, catalysis, mineral extraction processes, and the manufacturing of biosensors and ion-selective electrodes.
Liquid-Liquid Interfaces: Theory and Methods is a well-written, informative, one-stop resource that will save you time and energy in your search for the latest information on liquid-liquid interfaces.

Spis treści

Equilibrium Electric Potential Between Two Immiscible Electrolyte Solutions. Distribution Potential. Polarizability of the Liquid-Liquid Interface. Nonpolarized ITIES and Reference Potentials in Organic Phases. Free Energy of Coupling of Ion Transfer and Electron Transfer. Conclusions. References.
Volta and Surface Potentials at Liquid/Liquid Interfaces. Introduction. Electrified Liquid-Liquid Interfaces and Their Electrical Potentials. Volta Potential and Voltaic Cells. Voltaic Cells with Water/Nonpolar Liquid Interfaces. Voltaic Cells with Immiscible Electrolyte Solution Interface. Experimental Methods of Investigation of Voltaic Cells. Final Remarks. References.
Ion Solvation. The Relevant Properties of Ions. The Relevant Properties of Solvents. Quantities Describing Ionic Hydration. Transfer of Ions into Non-Aqueous Solvents. Preferential Ion Solvation in Mixed Solvents. References.
Adsorption Isotherms and the Structure of Oil/Water Interface. Introduction. Surface Solution Model. Analysis of the Generalized Frumkin Isotherm. Classical Isotherms as a Special Case of the Generalized Adsorption Isotherm. Adsorption Isotherm and the Structure of Interphase. Conclusion. References.
The Electrical Double Layer at Liquid-Liquid Interfaces. Introduction. Models of Electrolytes and Double Layers. Simulations of Solvents and Interfaces. Experimental Methods. Conclusions. References.
Second Harmonic Generation at Liquid/Liquid Interfaces. Introduction. Historical Overview. Theory. Experimental Apparatus. Surface SH Origin From Neat Liquid-Liquid Interfaces. Molecular Orientation at Liquid-Liquid Interfaces. Interfacial Chemical Equilibrium. Dynamics at Liquid-Liquid Interfaces. Surface Sum-Frequency Generation. Conclusion. References.
Quantum Theory of Charge Transfer. Physical Mechanism of Charge Transfer and the Role of Polar Medium. Outer-Sphere Solvent Reorganization Energy. Electron Transfer at the Interface and Specific Forms of the Solvent Reorganization Energy. Ion Transfer Across the Interface of Two Phases. References.
Kinetics of Charge Transfer. Ion Transfer. Electron Transfer. References.
Molecular Dynamics of Charge Transfer at the Liquid-Liquid Interface. Introduction. The Neat Interface. Electron Transfer. Ion Transfer. Conclusions and Outlook. References.
Photoelectrochemical Effect at Interface Between Two Immiscible Electrolytic Solutions. Introduction. Reactions of Charge Transfer at Liquid-Liquid Interfaces in Microheterogeneous Systems. Photoelectrochemical Effect at the Interface of Immiscible Electrolyte Solutions. Conclusion. References.
Excited State Electron Transfer at the Interface of Two Immiscible Electrolyte Solutions. Introduction. Electrochemical Probing of the ITIES. Electron Transfer Kinetics. Theory of Electron Transfer Rates Across Liquid-Liquid Interfaces (from Marcus and Benjamin). The Photochemical Redox Process. Photoeffects at the Polarized Liquid-Liquid Interface. Anomalous Photoeffects. Kinetics of Charge Transfer. The Instrumental System. Chemicals. The Future of ITIES Photoeffects. References.
Amperometric Ion-Selective Electrode Sensors. Introduction. Electrochemical Principle of Ion-Selective Electrode (ISE). Amperometric ISE Sensors. Amperometric ISE Biosensors
Electroanalytical Chemistry at Liquid-Liquid Interfaces. References.
Immiscible Liquid Interface and Self-Organized Assemblies of Lecithin. Introduction. Lecithin Self-Assembly and Self-Organization at the Interface. Interfacial Structures and Ternary Phase Diagrams. Electrointerfacial Phenomena. Methods. Prospects for Applications and Further Studies. References.
Phospholipid Monolayers and Phospholipases. Properties of Phospholipid Monolayers at ITIES. Charge Transfer Across the Phospholipid Monolayer at ITIES. Interfacial Enzymatic Reactions at ITIES. References.
Electrodialysis Through Liquid Ion-Exchange Membranes and Oil/Water Interface. Regularities of Electrodialysis Through Liquid Membranes. Application of Electrodialysis of Liquid Membranes. Experimental Apparatus. Conclusion. References.
Oil/Water Interfaces and the Origin of Life. Liquid-Liquid Interfaces and Chemical Evolution on the Early Earth. Environmental Conditions of the Prebiotic Earth. Sources of Prebiotic Organic Compounds. Membranes and Liquid-Liquid Interfaces. Photochemistry in the Prebiotic Environment: Synthesis of Amphiphiles. Proton Production by PAH in Hydrocarbon. Carbon Dioxide Reactivity in PAH-Alkane Systems. Conclusions. References.
Electrochemical Behavior of Drugs at the Oil/Water Interface. Introduction. Ion-Transfer Voltammetry at the Oil/Water Interface. Electrical Potential Oscillation Across a Liquid Membrane. Conclusion. References.
Electrocatalysis and Electrolysis. Introduction. Theory of Two Phase Electron Transfer Reactions. Model Systems. Electrocatalysis and Electrodeposition. Summary and Future Developments. References.
Subject Index

Shorter TOC (1 level)

O autorze

Volkov, Alexander G.; Deamer, David W.