Modern Aspects of Electrochemistry

ISBN-13: 9780306459689 / Angielski / Twarda / 1999 / 644 str.

Ralph E. White; John O'm Bockris; Brian E. Conway

Opis

Recognized experts present incisive analysis of both fundamental and applied problems in this continuation of a highly acclaimed series. Topics discussed include:

• A review of the literature on the potential-of-zero charge by Trasatti and Lust.
• A thorough review and discussion of nonequilibrium fluctuations in corrosion processes.
• A wide-ranging discussion of conducting polymers, electrochemistry, and biomimicking processes.
• Microwave (photo)electrochemistry, from its origins to today's research opportunities, including its relation to electrochemistry.
• New fluorine cell design, from model development through preliminary engineering modeling, laboratory tests, and pilot plant tests.
• A comprehensive account of the major and rapidly developing field of the electrochemistry of electronically conducting polymers and their applications.

These authoritative studies will be invaluable for researchers in engineering, electrochemistry, analytical chemistry, materials science, physical chemistry, and corrosion science.

Spis treści

1: The Potential of Zero Charge; S. Trasatti, E. Lust. I. Introductory Concepts. II. Experimental Aspects. III. Analysis of the Experimental Data. IV. Conclusions. V. References. 2: Nonequilibrium Fluctuations in Corrosion Process; R. Aogaki. I. Introduction. II. Active, Passive and Transpassive States of Metals. III. Nonequilibrum Fluctuations in Corrosion. IV. Conclusion. V. References. 3: Conducting Polymers, Electrochemistry and Biomimicking Processes; T. Fernández Otero. I. Introduction. II. Electropolymerization of Conducting polymers. III. Electrochemical versus Chemical Polymerization of Conducting Polymers. IV. Selfdoped Polymers, Polymeric Composites and Hybrid Materials. V. Physical Properties of Dry Conducting Polymers. VI. Electrochemical Properties. VII. Electrochemistry and Electrode Structures. VIII. Experimental Chronoamperograms and Chronocoulograms Under Conformational Relaxation Control. IX. Polymer-Solvent Interactions from the ESCR Model. X. Chronocoulograms Under Conformational Relaxation Control. XI. Voltammetry Under Conformational Relxation Control. XII. Experimental and Theoretical Voltammograms. XIII. Experimental and Theoretical Coulovoltagrams. XIV. Conducting Polymers as Soft and Nonstoichiometric Materials. Electrochemical Evidences. XV. Conducting Polymers as Three-Dimensional Electrodes at Molecular level. XVI. Soft, Wet and Complex Materials MimickingBiological Processes. XVII. Technological Applications of the ESCR Model. 4: Microwave (Photo)Electrochemistry; H. Tributsch. I. Introduction. II. Experimental. III. Theoretical Challenge. IV. Potential Dependent Stationary Microwave Conductivity Measurements. V. Potential Dependent Time Resolved Measurements. VI. Potential Dependent Periodical Measurements. VII. Oxides and Sensitization Cells. VIII. Microwave Phase Measurements. IX. Summary and Discussion. X. Acknowledgements. XI. References. XII. Figure Legends. 5: Improvements in Fluorine Generations; G.L. Bauer, W.V. Childs. I. Introduction. II. A Caution. III. The Challenge. IV. Acknowledgements. V. References.