The mid-infrared domain is a promising optical domain because it holds two transparency atmospheric windows, as well as the fingerprint of many chemical compounds. Quantum cascade lasers (QCLs) are one of the available sources in this domain and have already been proven useful for spectroscopic applications and free-space communications. This thesis demonstrates how to implement a private free-space communication relying on mid-infrared optical chaos and this requires an accurate cartography of non-linear phenomena in quantum cascade lasers.