This thesis proposes new approaches for modelling contacting interactions and electrostatic interactions between microparticles in the framework of the discrete element method and presents a systematic investigation on the agglomeration, migration and deposition of microparticles in presence of electrostatic and flow fields. It reports an exponential-form scaling for the size distribution of early-stage agglomerates in homogeneous isotropic turbulence and formulate the agglomeration and deagglomeration rates. The evolution of spherical clouds of charged particles that migrate under the action...