This guide is based on the synthesis of bisquinlone based phosphine ligands and desulfitative carbon-carbon bond forming reactions. It is divided into 3 chapters which include first an overview about heterocyclic BINAP analogues. In this chapter, survey of developing atropisomeric biheteroaryl backbone-containing bisphosphines, their designing concept, synthetic approaches and some of their important applications are discussed. Second, efficient synthesis of functionalized novel bisquinolone based mono- and diphosphine ligands of the aza-BINAP type. Preliminary studies confirm that these...