This book includes the details preparation methods of 3,3,3,3- and 4,4,4,4-tetraaminophthalocyaninatocopper(II) compounds and their grafting process with different prepared polymers. The sizing measurement showed that the grafting process led to decreasing in particle size and increasing in surface area. Optical measurements exhibited an increasing in the energy gap due to grafted polymers compared to ungrafted tetraaminophthalocyaninatocopper(II) and they were affected by their particle sizes. This was also reflected positively on their thermal properties.