Over the last few years, the classic synthesis of benzimidazoles has low yields and through complex routes. In the past thirty years organic thermochemistry has developed rapidly and led to a wealth of novel reactions and applications that can be of great significance. The present work has been devoted to study of thermal fragmentation of aromatic and heterocyclic amidoximes I-VI at 220-240oC alone and /or in the presence of naphthalene and tetralin as radical scavengers. The main feature of these thermolyses is the homolysis of the N-O and C-N bonds initiating different free radical...
Over the last few years, the classic synthesis of benzimidazoles has low yields and through complex routes. In the past thirty years organic thermoche...
