135 We first describe the thermodynamic theory of surface tension and adsorption, by the method of the dividing surface of GIBBS. The use of a dividing surface or its equivalent is indispensable for the treatment of a curved interface, as otherwise the concepts of the area and curvature of the interface, cannot be pre- cisely defined. In the case of a plane interface, however, the concept of the dividing surface is not necessary and a valid alternative exposition has been proposed by GUGGEN- HEIM 3J, 4J in treating the interface zone as a separate entity of some definite thickness bounded...
135 We first describe the thermodynamic theory of surface tension and adsorption, by the method of the dividing surface of GIBBS. The use of a dividin...