The astonishing progress in computer software and hardware technology in recent decades has established Computational Chemistry as a legitimate and exciting means of learning and exploring chemistry. Computational Chemistry has become a powerful tool for elucidating elusive mechanistic details of chemical reactions. An understanding of the detailed mechanistic pathways of organometallic reactions will drastically increase the ability to design and fine tune catalytic activities and selectivities and, thereby, sustain the importance, distinctiveness and vitality of the field. Density...