This book is aimed to provide an alternate synthetic protocol for the synthesis of desired ordered complexes and networks where a coordination complex has been used as the building block. We demonstrate that how simple ligands selectively coordinate a central or primary metal ion while leaving the appended functional groups as the peripheral secondary binding sites. These secondary binding sites upon coordination to metal ions afford heterometallic complexes as well as networks of highly ordered nature. The book starts with the introduction to the metalloligands as the molecular building...