The unique properties and applications of transition metal compounds have long fascinated both physicists and chemists. This volume presents theoretical and experimental studies for a deeper understanding of the electronic and vibronic properties of these compounds. In particular, an introduction into properties of spin sublevels of dd*, dA*, and AA* states is given, and a modern ligand field theory based on the Angular Overlap Model is presented. In experimental case studies it is shown how to characterize different types of electronic transitions using modern methods of laser spectroscopy....
The unique properties and applications of transition metal compounds have long fascinated both physicists and chemists. This volume presents theoretic...
Transition metal and rare earth compounds are investigated intensively because of important questions concerning fundamental research problems. More recently also their enormous potential for the development of new materials for photophysical and photochemical applications has been explored. Thus, it is important to focus on a deeper understanding of the elctronic energies, transition prohabilities, intermolecular interactions, etc.. This task has been accomplished by leading researchers in the field. They present introductions into, but also detailed reviews of the current state of knowledge...
Transition metal and rare earth compounds are investigated intensively because of important questions concerning fundamental research problems. More r...
The unique properties and applications of transition metal compounds have long fascinated both physicists and chemists. This volume presents theoretical and experimental studies for a deeper understanding of the electronic and vibronic properties of these compounds. In particular, an introduction into properties of spin sublevels of dd*, dA*, and AA* states is given, and a modern ligand field theory based on the Angular Overlap Model is presented. In experimental case studies it is shown how to characterize different types of electronic transitions using modern methods of laser spectroscopy....
The unique properties and applications of transition metal compounds have long fascinated both physicists and chemists. This volume presents theoretic...
There exists a large literature on the spectroscopic properties of copper(II) com- 9 pounds. This is due to the simplicity of the d electron configuration, the wide variety of stereochemistries that copper(II) compounds can adopt, and the f- xional geometric behavior that they sometimes exhibit 1]. The electronic and geometric properties of a molecule are inexorably linked and this is especially true with six-coordinate copper(II) compounds which are subject to a Jahn-T- ler effect.However, the spectral-structural correlations that are sometimes d- wn must often be viewed with caution as the...
There exists a large literature on the spectroscopic properties of copper(II) com- 9 pounds. This is due to the simplicity of the d electron configura...
The seventh of a series of prestigeous symposia on the photophysics and photochemistry of coordination compounds in 1987 called scientists from all over the world to the Castle of Elmau in the Bavarian Alps. Well-known researchers met to discuss recent advances in research. This proceedings volume of the 7th ISPPCC collects their contributions and provides an overview of theoretical and chemical aspects in six chapters: - Metal-centered excited states, - Photophysics and photochemistry of Cr(III) complexes, - Excited state properties of tris-2,2'-bipyridine-ruthenium(II) and related...
The seventh of a series of prestigeous symposia on the photophysics and photochemistry of coordination compounds in 1987 called scientists from all ov...
For a long time, the properties of transition metal and rare earth compounds have fascinated chemists and physicists from a scientific view-point, and more recently also their enormous potential as new materials has been explored. Applications in different fields have already been realized or are under c- rent investigation, for example, new laser materials, IR to visible upconversion systems, compounds for photolithographic processes, systems involving pho- redox processes for solar energy conversion, new photovoltaic devices, chemical sensors, biosensors, electroluminescent devices (OLEDs)...
For a long time, the properties of transition metal and rare earth compounds have fascinated chemists and physicists from a scientific view-point, and...