To understand hydrochemistry and to analyze natural as well as man-made impacts on aquatic systems, hydrogeochemical models have been used since the 1960's and more frequently in recent times. Numerical groundwater flow, transport, and geochemical models are important tools besides classical deterministic and analytical approaches. Solving complex linear or non-linear systems of equations, commonly with hundreds of unknown parameters, is a routine task for a PC. Modeling hydrogeochemical processes requires a detailed and accurate water analysis, as well as thermodynamic and kinetic data as...

Preface Uranium is a radioactive element and a heavy metal which is naturally occurring in ground and surface water. Although uranium is enriched in granites and gneiss ground water from these host rocks often shows low to intermediate uranium con centrations, while some ground waters from sandstone and carbonate aquifers show elevated uranium concentrations up to several hundred mg/1 without man made impact. On the other side, surface water contains increased anthropogenic uranium concentrations due to the intensive use of phosphate fertilizers and in mining areas due to mining and milling...

This second edition remains a comprehensive book on the subject. It offers beginners and advanced modelers alike a minimum theoretical background and a strong focus on the practical solution of geochemical modeling with PHREEQC.