The matrix isolation (MI) method has now been used for nearly thirty years. During this period it has been actively developed and the range of problems tackled greatly extended. Originally it was used for studies of transient species involv- ing vibrational, electronic and ESR spectroscopy. Nowadays the study of transient species forms a comparatively small part of HI work since it has been amply demonstrated that very fruitful information can be obtained of the structure and interactions of stable molecules and their aggregates. In addition to the s ectroscopic methods mentioned above the MI...

Proceedings of the NATO Advanced Study Institute, Les Arcs, France, July 13-25, 1986

The matrix isolation (MI) method has now been used for nearly thirty years. During this period it has been actively developed and the range of problems tackled greatly extended. Originally it was used for studies of transient species involv ing vibrational, electronic and ESR spectroscopy. Nowadays the study of transient species forms a comparatively small part of HI work since it has been amply demonstrated that very fruitful information can be obtained of the structure and interactions of stable molecules and their aggregates. In addition to the s ectroscopic methods mentioned above the MI...

In recent years, much concern has been expressed on the deleterious effects that anthropogenic emissions of acidic pollutants have on ecosystems of both industrialized countries and remote areas of the world. In many of these regions, seasonal snowcover is a major factor in the transfer of atmospheric pollutants, either to terrestrial and aquatic ecosystems or to the more permanent reservoirs of glaciers and ice sheets. The recognition of the role that seasonal snowcovers can thus play in the chemical dynamics of whole ecosystems was recently echoed by the Committee on Glaciology of the...