Studies of free radicals on surfaces are of interest for several reasons: the spontaneous or stimulated formation of radicals from adsorbed molecules may represent one possible mechanism for heterogeneous catalysis. In some cases the radicals are ionic, indicating that primary oxidation and reduction reactions occur. Radicals can also be used as probes to investigate diffusion processes on catalytic surfaces. The first direct observations were made more than 30 years ago, but detailed studies of structure, reactions and mobility have only recently become feasible with the advent of powerful...
Studies of free radicals on surfaces are of interest for several reasons: the spontaneous or stimulated formation of radicals from adsorbed molecules ...
It is now more than 20 years since the book "Radical Ions" edited by Kaiser and Kevan appeared. It contained aspects regarding generation, identification, spin density determination and reactivity of charged molecules with an odd number of electrons. New classes of reactive ion radicals have been detected and characterised since then, most notably cation radicals of saturated organic compounds. Trapping of electrons has been found to occur not only in frozen glasses but also in organic crystals. The structure and reactions of anion radicals of saturated compounds have been clarified during...
It is now more than 20 years since the book "Radical Ions" edited by Kaiser and Kevan appeared. It contained aspects regarding generation, identificat...
EPR of Free Radicals in Solids: Trends in Methods and Applications, 2nd ed. presents a critical two volume review of the methods and applications of EPR (ESR) for the study of free radical processes in solids. Emphasis is on the progress made in the developments in EPR technology, in the application of sophisticated matrix isolation techniques and in the advancement in quantitative EPR that have occurred since the 1st edition was published. Improvements have been made also at theoretical level, with the development of methods based on first principles and their...
EPR of Free Radicals in Solids: Trends in Methods and Applications, 2nd ed. presents a critical two volume review of the methods ...
Applications of EPR in Radiation Research is a multi-author contributed volume presented in eight themes: I. Elementary radiation processes (in situ and low temperature radiolysis, quantum solids); II: Solid state radiation chemistry (crystalline, amorphous and heterogeneous systems); III: Biochemistry, biophysics and biology applications (radicals in biomaterials, spin trapping, free-radical-induced DNA damage); IV: Materials science (polymeric and electronic materials, materials for treatment of nuclear waste, irradiated food); V: Radiation metrology (EPR-dosimetry, retrospective and...
Applications of EPR in Radiation Research is a multi-author contributed volume presented in eight themes: I. Elementary radiation processes (in situ a...
EPR of Free Radicals in Solids: Trends in Methods and Applications, 2nd ed. presents a critical two volume review of the methods and applications of EPR (ESR) for the study of free radical processes in solids. Emphasis is on the progress made in the developments in EPR technology, in the application of sophisticated matrix isolation techniques and in the advancement in quantitative EPR that have occurred since the 1st edition was published. Improvements have been made also at theoretical level, with the development of methods based on first principles and their...
EPR of Free Radicals in Solids: Trends in Methods and Applications, 2nd ed. presents a critical two volume review of the methods ...
EPR of Free Radicals in Solids: Trends in Methods and Applications presents methods and applications of modern EPR for the study of free radical processes in solids, which so far are only available in the journal literature. The first part of the book, covering trends in methods, contains experimentally oriented chapters on continuous wave and pulsed EPR techniques and special methods involving muon magnetic resonance and optical detection and theory for dynamic studies. New simulation schemes, including the influence of dynamics, are presented as well as advances in the calculation of...
EPR of Free Radicals in Solids: Trends in Methods and Applications presents methods and applications of modern EPR for the study of free radical proce...
Applications of EPR in Radiation Research is a multi-author contributed volume presented in eight themes: I. Elementary radiation processes (in situ and low temperature radiolysis, quantum solids); IV: Materials science (polymeric and electronic materials, materials for treatment of nuclear waste, irradiated food);
Applications of EPR in Radiation Research is a multi-author contributed volume presented in eight themes: I. Elementary radiation processes (in situ a...