There are essentially two theories of solutions that can be considered exact: the McMillan Mayer theory and Fluctuation Solution Theory (FST). The first is mostly limited to solutes at low concentrations, while FST has no such issue. It is an exact theory that can be applied to any stable solution regardless of the number of components and their concentrations, and the types of molecules and their sizes. Fluctuation Theory of Solutions: Applications in Chemistry, Chemical Engineering, and Biophysics outlines the general concepts and theoretical basis of FST and provides a range of...
There are essentially two theories of solutions that can be considered exact: the McMillan Mayer theory and Fluctuation Solution Theory (FST). The ...