This is the first of two volumes devoted to probability theory in physics, physical chemistry, and engineering, providing an introduction to the problem of the random walk and its applications. In its simplest form, the random walk describes the motion of an idealized drunkard and is a discreet analogy of the diffusion process. A thorough account is given of the theory of random walks on discreet spaces (lattices or networks) and in continuous spaces, including those processed with random waiting time between steps. Applications discussed include dielectric relaxation, charge transport in the...