This book presents investigation results of thermal transformations in thermoresistant polymers: polysulfones, polyester-imides, aliphatic-aromatic polyimides and polyamides, liquid-crystal aromatic co-polyesters, polyphenylquinoxalines at temperatures of materials and articles processing and operation. An important result of investigations is the determination of thermooxidative degradation regularities for aliphatic-aromatic heterochain polymers and description of the degradation mechanism. The applied aspect of this work is the approach to stabilization of thermoresistant polymers and...
This book presents investigation results of thermal transformations in thermoresistant polymers: polysulfones, polyester-imides, aliphatic-aromatic po...
Data on polysite phenomenon (distribution of active sites by kinetic activity and stereospecificity of action) in polymerization are analyzed. The examples of polysite phenomenon manifestation and assessment, and its connection with ion, ion-coordination and radical polymerization conditions for olefins and dienes are shown. Geometrical and electron structure of active sites in ion-coordination polymerization of dienes is considered and the relation between the structure, reactivity and stereospecificity of action of different site types is shown.
Data on polysite phenomenon (distribution of active sites by kinetic activity and stereospecificity of action) in polymerization are analyzed. The exa...
This volume deals with chemistry of polyelectrolytes, namely biocide guanidine containing polymers, discussing both synthesis of new guanidine containing monomers of diallyl and acrylic nature and their structure and investigation of their radical (co)polymerization and properties of new (co)polymers. The first parts of the book describe radical polymerization of these monomers and their co-polymerization with diallyldialkylammonium derivatives, features of their kinetic behavior in these processes (for example, polymerization rates, reactivity ratios) The sections on phycal chemical methods...
This volume deals with chemistry of polyelectrolytes, namely biocide guanidine containing polymers, discussing both synthesis of new guanidine contain...
The aim of this book is to elucidate the complicated problem concerning the connection between the structure and mechanism of oxidation of heterogeneous and heterophase polymer systems. The material presented in this book concerns the specific features of the kinetics of oxidation and those of the structure of polymer systems.
The aim of this book is to elucidate the complicated problem concerning the connection between the structure and mechanism of oxidation of heterogeneo...
