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Several approaches to the synthesis of a natural acetyl cholinesterase (AChE) inhibitor, cyclophostin and an isosteric endophosphonate analog were explored. These bicyclic molecules posses a novel seven membered cyclic enolphosphate/phosphonate ring fused to a butyrolactone. Two basic synthetic strategies: a) lactonization followed by the seven membered ring formation and b) the seven membered ring synthesis followed by lactonization, were applied in these syntheses. The synthesis of the endophosphonate analog, following strategy a, gave an unexpected enolether lactone molecule. ...

The book provides various EdgeAI concepts related to its architecture, key performance indicators, and enabling technologies after introducing algorithmic government, large-scale decision-making, and computing issues in the cloud and fog. With advancements in technology, artificial intelligence has permeated our personal lives and the fields of economy, socio-culture, and politics. The integration of artificial intelligence (AI) into decision-making for public services is changing how governments operate worldwide. This book discusses how algorithms help the government in various ways,...