Atomistic View of Mineral-adsorbate Interface : Investigation of Fluorapatite (100) Surface and its Interface with Biomolecules Using Grazing Incidence X-ray Diffraction

ISBN-13: 9783639114003 / Angielski / Miękka / 2009 / 192 str.

Aparna Pareek

Opis

Apatite is an important biomineral, which constitutes the endoskeleton (bones and teeth) in vertebrates including humans. The interaction between the apatite surface and biological environment plays a key role in biomineralization. To understand the interaction between apatite and inorganic species, atomic scale information of the apatite surface and the apatite biomolecular interface is required. In this work, the structure of fluorapatite (100) surface was first investigated in dry environmental conditions using Grazing Incidence X-ray Diffraction (GIXRD). Further, to understand the apatite biomolecular interface, experiments were performed under humid and completely hydrated conditions, which were then followed by apatite aqueous glycine interface study. Measurement and analyses of specular and non-specular crystal truncation rods in all cases provided information about the surface structure of the mineral and sites of adsorption at the atomic scale. Simulation studies supported the experimental results.

O autorze

Aparna Pareek, received the title of Dr. rer. Nat. from Ruhr
University Bochum, Germany. Currently working as a Postdoctoral
fellow at the Max-Planck Institute for Iron Research,
Dusseldorf, Germany.