Water in Confining Geometries

ISBN-13: 9783540004110 / Angielski / Twarda / 2003 / 472 str.

Opis

The evolution of the physical/ chemical sciences towards understanding the behavior of matter at the molecular level has been accompanied by a rapid increase in studies of the properties and functioning of confined water; that is, water in small clusters and nanoparticles or confined to solid/liquid thin films, surfaces and interfaces. These studies represent a convergence of interests and methodologies. That is, much emerging science, both basic and applied, depends on an understanding of confined water for significant advances; and the technical ability to gain that understanding has evolved only during the past decade or two. Firm concepts of the behavior of water in a variety of confining geometries are basic to advances in molecular biology, weather phenomena, atmospheric chemistry, interstellar and interplanetary physics and chemistry; as weIl as to the complete understanding of properties of macroscopic amounts of water and water-solute systems. In recognition of the growing importance of studies of confined water, a Telluride (Colorado) workshop was convened in August of 2000. This was an exceptionally strong 5-day conference with numerous informative talks by leading scientists on both basic and applied aspects of the subject. Lively discussions left the participants spent.

Spis treści

I Water Clusters.- 1 Nature of Many-Body Forces in Water Clusters and Bulk.- 2 Thermochemistry and Kinetics of Evaporation and Condensation for Small Water Clusters.- 3 Vibrational Spectroscopy and Reactions of Water Clusters.- 4 Solvent Effects of Individual Water Molecules.- 5 Solvation Effects on the Properties and Reactivities of Ionic and Neutral Water Clusters.- II Water at Interfaces.- 6 Properties of Water Clusters on a Graphite Sheet.- 7 Phase Equilibria and Transitions of Confined Systems in Hydrophobic and Aqueous Environments.- 8 Thin Film Water on Insulator Surfaces.- 9 Protein Hydration Water.- 10 Computational Studies of Liquid Water Interfaces.- 11 Water Confined at the Liquid-Air Interface.- III Atmospheric and Astrophysical Water and Ice.- 12 Physical Properties and Atmospheric Reactivity of Aqueous Sea Salt Micro-Aerosols.- 13 Interactions and Photochemistry of Small Molecules on Ice Surfaces: From Atmospheric Chemistry to Astrophysics.- IV Amorphous Solid Water (ASW) Films.- 14 Molecular Beam Studies of Nanoscale Films of Amorphous Solid Water.- 15 Microporous Amorphous Water Ice Thin Films: Properties and Their Astronomical Implications.- V Ice Particles.- 16 Nucleation of Ice in Large Water Clusters: Experiment and Simulation.- 17 Ice Nanoparticles and Ice Adsorbate Interactions: FTIR Spectroscopy and Computer Simulations.

Blurb

Written by leading experts in this field, this book gives a wide-ranging and coherent treatment of water in confining geometries. This includes water in clusters, particles, films, and at surfaces and interfaces. The topics covered range from the molecular to condensed phases and involve both liquid and solid phases. Emphasis is on systems for which the extent of water is limited so that the surface/interface of the water may be critical to the properties of the system. The main sections include: theoretical studies of intermolecular interactions; neutral and ionic water clusters; solid and liquid water surfaces and interfaces; amorphous ice layers; ice and water particles; water in bio-systems; and atmospheric water.