1. Introduction to Vat Polymerization 3D Printing Technologies 2. Fundamental Chemistry in Vat Photopolymerization 3. Vat Photopolymerization 3D Printing of Functional Materials 4. Vat Photopolymerization 3D Printing of Engineering Plastics 5. Vat Photopolymerization 3D Printing of Ceramics 6. Vat Photopolymerization 3D Printing of Structures 7. Vat Photopolymerization 3D Printing Applications in Engineering 8. Vat Photopolymerization 3D Printing Applications in Bioengineering 9. Vat Photopolymerization 3D Printing Applications in Electronics 10. Vat Photopolymerization 3D Printing Applications in Metamaterials 11. Vat Photopolymerization 3D Printing Applications in Bio-inspired Structures and Functions 12. Trends, Prospects, and Outlook of Vat Polymerization 3D Printing