The Thermodynamics of Phase and Reaction Equilibria

ISBN-13: 9780444594976 / Angielski / Twarda / 2012 / 744 str.

Ismail Tosun

Opis

This book provides a sound foundation for understanding abstract concepts of phase and reaction equilibria (e.g. partial molar Gibbs energy, fugacity, and activity), and shows how to apply these concepts to solve practical problems using numerous clear examples. It also presents numerical methods necessary for solving real-world problems as well the basic mathematics needed, facilitating its use as a self-study reference work. In the example problems requiring MATHCAD^(R) for the solution, the results of the intermediate steps are given, enabling the reader to easily track mistakes and understand the order of magnitude of the various quantities involved.

• Clear layout, coherent and logical organization of the content, and presentation suitable for self-study
• Provides analytical equations in dimensionless form for the calculation of changes in internal energy, enthalpy, and entropy as well as departure functions and fugacity coefficients
• Includes up-to-date information, comprehensive in-depth content and current examples in each chapter
• Includes many well organized problems (with answers), which are extensions of the examples enabling conceptual understanding for quantitative/real problem solving
• Includes the mathematical background required for solving problems encountered in phase and reaction equilibria

Recenzje

"This detailed thermodynamics text from Tosun is designed for a graduate or upper-level undergraduate course.Differential calculus is utilized throughout, and each chapter opens with a summary of mathematical techniques needed to learn the upcoming material." --Reference and Research Book News, October 2013

Spis treści

1. Review of the First and Second Laws of Thermodynamics2. Thermodynamic Properties of Real Substances3. Calculation of Changes in Internal Energy, Enthalpy, and Entropy4. Equilibrium and Phase Stability in One-Component Systems5. Fugacity of a Pure Component6. Thermodynamics of Mixtures7. Fugacity of a Component in a Mixture8. Excess Mixture Properties and Activity Coefficients9. Vapor-Liquid Equilibrium10. Solubility of Gases in Liquids11. Liquid-Liquid Equilibrium12. Phase Equilibria Involving Dissolved Solids in Liquids13. Chemical Reaction Equilibrium14. Heterogeneous Reactions and Multireaction Equilibria

O autorze

The author has been teaching undergraduate and graduate level thermodynamics courses for over 40 years. Since 1980 he has been a faculty member at the Middle East Technical University (METU), Ankara, Turkey. He has also taught at the Turkish Military Academy and the University of Akron, Ohio. Professor Tosun received his BS and MS degrees from METU, and a PhD degree from the University of Akron, all in chemical engineering. His research interests include mathematical modeling and transport phenomena.

Professor Tosun is the author of the following books:
. Modeling in Transport Phenomena - A Conceptual Approach, 2nd ed., Elsevier, 2007.
. Fundamental Mass Transfer Concepts in Engineering Applications, CRC Press, 2019.
. Thermodynamics - Principles and Applications, 2nd ed., World Scientific, 2020.