Surfactants in Solution: Volume 4

ISBN-13: 9781461290230 / Angielski / Miękka / 2011 / 550 str.

K. L. Mittal; P. Botherel

Opis

This and its companion Volumes 5 and 6 document the proceedings of the 5th International Symposium on Surfactants in Solution held in Bordeaux, France, July 9-13, 1984. This symposium was the continuation of the series of symposia initiated in 1976 in Albany, New York under the title "Micellization, Solubilization and Microemulsions." The next two symposia were labelled "Solution Chemistry of Surfactants" and "Solution Behavior of Surfactants: Theoretical and Applied Aspects" held in Knoxville, TN in 1978 and Potsdam, N. Y. in 1980, respectively. In 1982 at the time of the 4th Symposium in this series, it became amply evident that there was a definite need to have more a generic title to describe these biennial events, and after much deliberation it was decided that an appropriate title would be "Surfactants in Solution" as both the aggregation and adsorption aspects of surfactants were addressed. So the 4th Symposium was held in 1982 in Lund, Sweden, under this new rubric, and it was decided to continue these symposia in the future under this appellation. Naturally, the Bordeaux Symposium was dubbed as the 5th International Symposium on Surfactants in Solution, and our logo became SIS which is very apropos and appealing. It was in Bordeaux that the decision was made to hold the 6th SIS Symposium in New Delhi and it is scheduled for August 18-22, 1986 in the capital of India.

Spis treści

of Volume 4.- I. Aggregation of Surfactants, and Structure, Dynamics and Characterization of Micelles.- Physical Principles of Surfactant Self-Association Into Micelles, Bilayers, Vesicles and Microemulsion Droplets.- Statistical-Thermodynamic Theory of Surfactant Organization in Micelles and Bilayers.- Model For Thermodynamics of Ionic Surfactant Solutions: Enthalpies, Heat Capacities, Volumes, Expansibilities, and Compressibilities.- Model For Thermodynamics of Ionic Surfactants: Effect of Electrolytes on Osmotic and Activity Coefficients.- Thermodynamic Behaviour of Sodium Deoxycholate, Sodium Dodecylsulphate and Sodium Tetradecylsulphate Micellar Solutions.- Molar Volumes of Cationic Surfactants in KC1 and NaCl Concentrated Salt Solutions.- Excimer-Monomer Emission in Alkylbenzenesulfonates: A New Technique for Determining Critical Micellar Concentrations.- Dynamics of Organized Assemblies in Solution.- Micelle Structure in Aqueous Solutions of Polyoxyethylene Surfactants.- Neutron and X-ray Comparative Study of Direct Ionic Micelles.- Small-Angle Neutron Scattering From Aqueous Solutions of C12 E6 and C12 E8 : Critical Fluctuations and Micellar Growth 12.- Positronium Diffusivity- and Lifetime Parameters and the Micellar Structure in Aqueous (D2O) Solutions.- Raman Scattering in Aqueous Solutions of Sodium Dodecyl Sulfate.- The Influence of Electrostatic Repulsions on Micellar Diffusivities Obtained by Dynamic Light Scattering: Experiment vs. Theory.- Quasielastic Light Scattering on Tetradecyltrialkylammonium Bromide.- Effect of Electrolytes and Hydrocarbons on the Cloud Point Transition of C12 E8 Solutions.- Structural and Dynamic Consequences of Amphiphile Hydration: Their Origin and Analytical Molecular Force Theory.- Electron Spin Echo Modulation Studies of Doxylstearic Acid Nitroxide Spin Probe Locations in Micelles.- Critical-type Behavior and Micellar Growth Observed in an Ionic Surfactant/Salt System.- Perturbation of Micellar Size and Charge by Addition of t-Amyl Alcohol.- Anionic Surf actants With Divalent Gegenions of Diffuse or Separate Electric Charge: Solubility and Micelle Formation.- Effect of Alcohol and Oil on the Dynamics of Micelles.- Structural Changes in Aqueous Micellar Systems of an Anionic and a Cationic Surfactant.- Scaling Laws in Semi-Dilute Aqueous Solutions of Alkyltrimethylammonium and Alkylpyridinium Bromides.- Effect of Added Oil on Aqueous Alkyltrimethylammonium Bromide Micelles in the Presence of Alcohol.- Influence of Dissolved Additives on the Critical Micellar Concentration of Surfactants.- The Influence of Solubilized Additives on Surfactant Solutions Containing Rodlike Micelles.- The Interaction of 2-Naphtholate Ion With Some Cationic Surfactants in Aqueous Solution.- Strengthening of Hydrophobic Bonding and the Increase in the Micellar Degree of Ionization in Cetyltrimethyl-Ammbnium Bromide Aqueous Solutions by Amphiphiles and the Micelle-Water Distribution Coefficient.- Nonideality of Mixing of Micelles.- Mixed Micelles of Dodecyltrimethy lammonium Bromide with Sodium Dodecyl Sulfate Studied by ESR of Nitroxide Probes.- Mixed Micelle Structure: Cosurfactant and Charge Influence.- Photon Correlation Studies on the Micelles of a Poly(Oxyethylene)-Poly(Oxypropylene) - Poly (Oxyethylene) Block opolymer in Aqueous Solution.- II. Phase Diagrams and Phase Behavior of Surfactant Solutions.- On the Theory of Micellar Size in Isotropic and Nematic Surfactant Solutions.- Applications of Catastrophe Theory to Surfactant-Oil- Brine Equilibrated and Emulsified Systems.- Molecular Order and Dynamics in Short Chain Alkylphosphate/Water Mesophases.- Critical Fluctuations, Micelle Kinetics and Phase Diagram of Water - Nonionic Surfactant, H2O - C12E6.- Modelling of Phase Behavior of Micellar Systems Used for Enhanced Oil Recovery.- Staining and Drying-Induced Artifacts in Electron Microscopy of Surfactant Dispersions; III: Evidence from Optical Microscopy and a Negative Staining Case.- Phase Behavior of SDS/AOT/Water Systems.- Aggregation and Dynamical Behavior in Sodium Diethylhexyl Phosphate/Water/Benzene Inverted Micelles.- Three Dimensional Phase Diagram of Nonionic Surfactants: Effect of Salinity and Temperature.- Water Dynamics in Micellar and Lyotropic Phases-of the Dodecylammonium Chioride/D20 System by 2H and 17O Nuclear Magnetic Relaxation.- Study of Salt Partitioning in Winsor II Systems.- About the Contributors.