Olefin Upgrading Catalysis by Nitrogen-based Metal Complexes I: State-of-the-art and Perspectives

ISBN-13: 9789048138142 / Angielski / Twarda / 2011 / 288 str.

Giuliano Giambastiani;Juan Campora

Opis

On the threshold of the 50th anniversary of the Noble Prize to Ziegler and Natta, this book highlights key advances in the field of olefin conversion in recent years. There is focus on olefin polymerization, co-polymerization, and oligomerization processes.

Spis treści

Preface. - 1. Cr Complexes of Nitrogen Donor Ligands for Olefin Oligomerisation and Polymerisation David S. McGuinness .- 2. Late-transition metal complexes with mixed N^O, N^S, N^P chelating ligands for olefin polymerization catalysis Andrea Ravasio, Laura Boggioni and Incoronata Tritto.- 3. Rare-earth metal complexes supported by nitrogen-containing ligands in olefin polymerization Alexander A. Trifonov.- 4. Imine-based Vanadium Catalysts for -olefin Polymerization Carl Redshaw.- 5. Imino- and Amido-Pyridinate d-Block Metal Complexes in Polymerization/Oligomerization Catalysis Giuliano Giambastiani, Lapo Luconi, Roger L. Kuhlman and Phillip D. Hustad

Blurb

Olefin Upgrading Catalysis by Nitrogen-based Metal Complexes provides a critical review of the state-of-the-art developments in industrially relevant processes connected to efficient and selective olefin upgrading. Specific attention is devoted to catalysts containing imine- and amine-based ligands.

All the chapters in this book have been designed to provide a systematic account of the vast amount of information available for this type of catalyst as well as to highlight the factors that ultimately control the catalyst’s performance and productivity. A comprehensive panorama of catalyst precursors is presented, spanning from group 10 α-diimine complexes and iron and cobalt 2,6-bis(imino)pyridine derivatives, to vanadium, chromium, titanium, zirconium and lanthanide complexes supported by nitrogen-containing ligands. The authors of this collective work are currently involved in the development of imine-based catalysts for efficient and selective olefin upgrading and the majority of them have dedicated most of their scientific career to this important field. In writing this book, their major goal is to transfer as many ideas and experiences as possible to the global audience of scientists engaged in this area of research.