ISBN-13: 9781118888162 / Angielski / Twarda / 2014 / 552 str.
ISBN-13: 9781118888162 / Angielski / Twarda / 2014 / 552 str.
The Magnesium Technology Symposium, the event on which this collection is based, is one of the largest yearly gatherings of magnesium specialists in the world. Papers represent all aspects of the field, ranging from primary production to applications to recycling. Moreover, papers explore everything from basic research findings to industrialization. Magnesium Technology 2014 covers a broad spectrum of current topics, including alloys and their properties; cast products and processing; wrought products and processing; forming, joining, and machining; corrosion and surface finishing; ecology; and structural applications. In addition, there is coverage of new and emerging applications in such areas as hydrogen storage. The collection includes more than 70 papers, including unpublished papers from the 2013 symposium.
The Magnesium Technology Symposium, the event on which this impressive collection is based, is one of the largest yearly gatherings of magnesium specialists in the world. (Metall, 1 Octoer 2014)
Preface xiii
About the Editorsxv
Session Chairs xix
Reviewer Pool xxi
Keynote Session
Automotive Magnesium: Impacts and Opportunities 3
W. Joost
Alloy Development, Manufacturing and Design for Magnesium Applications 5
A. Luo
Life Cycle Assessment of Eco–Magnesium Alloy Produced by Green Metallurgy EU Project Process Route 7
F. D′Errico, G. Plaza, F. Giger, and S. Kim
The IMA Study on the Life Cycle Assessment (LCA) of Magnesium 13
H. Friedrich, and S. Ehrenberger
Dynamic Behaviour of a Rare Earth Containing Mg Alloy, WE43B–T5, Plate with Comparison to Conventional Alloy, AM30–F 15
S. Agnew, W. Wittington, A. Oppedal, H. El Kadiri, M. Shaeffer, K. Ramesh, J. Bhattacharyya, R. DeLorme, and B. Davis
Thermodynamic and Kinetic Calculations for TRC (Twin Roll Casting) Mg Alloy Design 17
I. Jung and M. Paliwal
Powders, Recycling, Hydrometallurgy, Primary Production, and Creep
Emerging Applications Using Magnesium Alloy Powders: A Feasibility Study 21
R. Tandon and D. Madan
Isothermal Hydrogenation Kinetics Study of Magnesium Hydride with TiH2 Additive 27
J. Li, P. Fan, C. Zhou, and Z. Fang
Magnesium Electrorefining in Non–Aqueous Electrolyte at Room Temperature 31
K. Kwon, J. Park, P. Kusumah, B. Dilasari, H. Kim, and C. Lee
Recovery of Rare Earth Metals in Used Magnets by Molten Magnesium 35
T. Akahori, Y. Miyamoto, T. Saeki, M. Okamoto, and T. Okabe
Recovery of Magnesium and Recycling of Spent Solution in Chloride–Based Atmospheric Acid Leaching of Nickel Laterite 39
Y. Ge, W. Ding, D. Tan, and S. Guo
Effect of Physical Properties of Dolomite on Carbothermic Reduction 43
S. Wang, Y. Wang, G. Bin, and J. Diao
Time Dependent Springback of a Magnesium Alloy 49
B. Li, Z. McClelland, S. Horstemeyer, I. Aslam, P. Wang, and M. Horstemeyer
Precipitate Formation in Uniaxially Stressed High Pressure Die Cast Binary Mg–Nd Alloy during Creep Testing 55
D. Choudhuri, S. Nag, N. Dendge, M. Gibson, and R. Banerjee
A Review of the Influence of Production Methods and Intermetallic Phases on the Creep Properties of AZ91 59
P. Roodposhti, A. Sarkar, and K. Murty
Indentation Creep Behavior of Mg–10Gd–3Y–0.5Zr (wt.%) Alloy at Elevated Temperatures 65
H. Wang, Q. Wang, and J. Yuan
Deformation I
The Athermal Component of the Strength of Binary Mg Solid Solutions 73
S. Abaspour and C. Cáceres
Crack Propagation under Bending in Cast Mg10GdxNd–T4 Alloys 77
P. Maier, C. Mendis, M. Wolff, and N. Hort
High Shear Deformation to Produce High Strength and Energy Absorption in Mg Alloys 83
V. Joshi, S. Jana, D. Li, H. Garmestani, E. Nyberg, and C. Lavender
As–Cast Microstructure and Texture of Twin–Roll Cast AZ31 89
M. Masoumi, F. Zarandi, and M. Pekguleryuz
Post Deformation Annealing Behaviour of Mg–Al–Sn Alloys 95
A. Kabir, J. Su, M. Sanjari, I. Jung, and S. Yue
Acoustic Emission Analysis of Plane Strain–Compressed Mg Single Crystals 101
D. Drozdenko, P. Dobro, M. Knapek, D. Letzig, J. Bohlen, and F. Chmelík
Precipitation Strengthening of a Mg–Zn Alloy in Tension and Compression 105
J. Rosalie, H. Somekawa, and A. Singh
Characterization of Damage in Magnesium Using Digital Image Correlation and Electron Backscattered Diffraction Patterning 111
M. Nemcko, P. Mas, M. Bruhis, and D. Wilkinson
Low Cycle Fatigue Properties of Extruded Mg10GdxNd Alloys 115
G. Tober, P. Maier, S. Müller, and N. Hort
Quantification of Microstructure–Properties–Behavior Relations in Magnesium Alloys Using a Hybrid Approach 121
K. Hazeli, J. Cuadra, P. Vanniamparambil, R. Carmi, and A. Kontsos
Deformation II
Dislocation Activity in AZ31B Magnesium Deformed at Moderately Elevated Temperatures via EBSD 127
T. Ruggles, A. Khosravani, D. Fullwood, and M. Miles
Deformation, Recrystallization and Grain Growth Behavior of Large–Strain Hot Rolled Binary Mg–1Dy Alloy 133
I. Basu and T. Al–Samman
Strain Recrystallization and Grain Growth in AZ31B–H24 Magnesium Alloy Sheet 139
A. Antoniswamy, J. Carter, L. Hector Jr., and E. Taleff
Deformation Behavior and Dynamic Recrystallization of Micro–Alloyed Mg–Al–Ca Alloys during High Temperature Deformation 143
J. Su, A. Kabir, I. Jung, and S. Yue
Physically–Based Model for Static Recrystallization in AZ31 149
P. Okrutny, S. Liang, L. Meng, and H. Zurob
The Role of Deformation Modes on Ductility and Dynamic Recrystallization Behavior of AZ31 Mg Alloy at Low Temperatures 155
E. Dogan, M. Vaughan, C. Hayrettin, I. Karaman, and G. Ayoub
Effect of Microstructure on Deformation and Fracture of Thixomolded and Thermomechanically Processed AZ61 161
T. Berman, W. Donlon, R. Decker, T. Pollock, and J. Jones
Microstructure Evolution and Mechanical Properties of Mg–14%Li–1%Al Alloy during the High–Pressure Torsion 167
C. Tian, H. Lu, and L. Zhao
Melting, Modeling, and Solidification
Finite–Element Analysis of Melt Flow in Horizontal Twin–Roll Casting of Magnesium Alloy AZ31 173
J. Park
Nucleation and Growth of Metastable Phases in Mg–Nd, Mg–Gd and Mg–Gd–Nd Based Alloys 179
S. El Majid, G. Atiya, M. Bamberger, and A. Katsman
A Numerical and Experimental Study of Flow Behavior in High Pressure Die Casting 185
M. Saeedipour, S. Schneiderbauer, S. Pirker, and S. Bozorgi
In Situ Synchrotron Radiation Diffraction during Melting and Solidification of Mg–Al Alloys Containing CaO 191
B. Wiese, C. Mendis, D. Tolnai, G. Szakacs, A. Stark, N. Schell, H. Reichel, R. Bruckner, K. Kainer, and N. Hort
Solidification Characteristics of Wrought Magnesium Alloys Containing Rare Earth Metals 197
A. Javaid, F. Czerwinski, R. Zavadil, M. Aniolek, and A. Hadadzadeh
Strengthening due to the Percolating Eutectic Microstructure in Squeeze Cast MRI230D 203
B. Zhang, A. Nagasekhar, and C. Cáceres
Effect of Al Addition on Microstructure of AZ91D 209
U. Joshi and N. Babu
In Situ Synchrotron Radiation Diffraction during Solidification of Mg4Y and Mg4YxGd Alloys (x = 1, 4 wt.%) 213
G. Szakács, B. Wiese, C. Mendis, D. Tolnai, A. Stark, N. Schell, M. Nair, K. Kainer, and N. Hort
A New Method for Melting Mg–Li Alloys 219
L. Gong, J. Zhang, T. Yin, J. Wei, and G. Wu
Texture and Wrought Processing I
Deformation Behavior of ZE10 Magnesium Alloy Sheet 227
P. Dobron, J. Balík, F. Chmelík, K. Illková, D. Drozdenko, J. Bohlen, D. Letzig, and P. Lukac
Texture Evolution during Grain Growth of Magnesium Alloy AZ31B 233
J. Bhattacharyya, B. Radhakrishnan, G. Muralidharan, and S. Agnew
Effect of Annealing on Microstructure, Texture and Tensile Properties of Twin–Roll Cast AZ31B 239
M. Masoumi, F. Zarandi, and M. Pekguleryuz
Influence of Rolling Direction and Temperature on the Texture Formation in Rolled AZ31B Magnesium Alloy 245
L. Catorceno and N. de Lima
Texture Evolution during Wire Drawing of Mg–RE Alloy 251
M. Chatterton, J. Robson, and D. Henry
Extrusion of Hollow Magnesium Profiles and Investigation of Extrusion Seams 257
F. Gensch, R. Nitschke, S. Gall, and S. Müller
Microstructural Evolution and Its Relationship to the Mechanical Properties of Mg AZ31B Friction Stir Back Extruded Tubes 263
J. Milner and F. Abu–Farha
Effect of Yttrium Addition on Texture Development in a Cast Mg–Al–Y Magnesium Alloy during Compression 269
N. Tahreen, D. Chen, M. Nouri, and D. Li
Wrought Processing II and Joining
Spike–Forging of As–Cast TX32 Magnesium Alloy 275
K. Rao, K. Suresh, N. Hort, and K. Kainer
An Introduction to the Forging of Elektron43 – A High Performance Wrought Magnesium Alloy 281
D. Henry, M. Turski, P. Lyon, and T. Wilks
Structure and Properties of Interlayer Formed between Magnesium Alloy Core and Aluminium Alloy Coating during Deformation 285
S. Boczkal, P. Korczak, B. Plonka, W. Szymanski, and M. Nowak
A Novel Process for Producing Large Scale Mg–Sheets 289
G. Norbert, E. Marcus, N. André, K. Christian, H. Sven, B. Bernd–Arno, and H. Maier
Effect of Volume Fraction of Icosahedral Phase in CaO Added Mg–Zn–Y Alloys 293
H. Lim, D. Kim, T. Kwak, W. Yang, H. Kim, Y. Yoon, and S. Kim
Effect of CaO on Hot Workability and Microstructure of Mg–9.5Zn–2Y Alloy 297
T. Kwak, D. Kim, J. Yang, Y. Yoon, S. Kim, H. Lim, and W. Kim
Welding of Dissimilar Light Metals by Disk Laser 301
M. Sahul, M. Turna, and M. Sahul
Design of Binary Zinc–Based Solder for Joining Mg Alloy Type AZ 31 B 307
M. Jana, M. Turna, and M. Ozvold
Friction Stir Welding of Magnesium Alloy Type AZ 31 311
T. Kupec, M. Behúlová, M. Turna, and M. Sahul
Corrosion and Coatings
Enhancing Corrosion Resistance by a Hydrophobic Surface Feature for Magnesium Alloy AZ91D 319
X. Chen, C. Ke, and N. Birbilis
Oxidation and Corrosion Behavior of Non–Flammable Magnesium Alloys Containing Ca and Y 325
B. You, Y. Kim, C. Yim, and H. Kim
Corrosion Behavior of Magnesium Alloys Containing Sn and Zn 331
C. Yim, S. Woo, J. Yang, and B. You
Effect of Surface Condition on the Localized Corrosion Behavior of Magnesium Alloy AZ31B 335
Z. Cano, J. Kish, and J. McDermid
Formation of Self–Assembled Monolayer on Cerium Conversion Coated AZ31 Mg Alloy 341
S. Salman, N. Akira, K. Kuroda, and M. Okido
Effects of Current Density on Microstructure and Corrosion Property of Coating on AZ31 Mg Alloy Processed via Plasma Electrolytic Oxidation 345
K. Lee, F. Einkhah, M. Sani, Y. Ko, and D. Shin
Corrosion–Stress Relaxation Effects on Tensile Properties of an AZ61 Magnesium Alloy 351
H. Martin, C. Walton, K. Bruce, A. Hicks, M. Horstemeyer, W. Whittington, and P. Wang
Corrosion Behavior of Friction Stir Welded AZ31 Joints for Automotive Applications 357
X. Zhang, Z. Cano, B. Wilson, J. Kish, and J. McDermid
Biomedical Applications
Development of a Generalised Understanding of Environmentally–Assisted Degradation of Magnesium–Aluminium Alloys 365
N. Winzer, H. Höpfel, and P. Casajus
Coating Systems for Biodegradable Magnesium Applications 371
J. Seitz, R. Eifler, M. Vaughan, C. Seal, M. Hyland, and H. Maier
Improvement of Cytocompatibility of Magnesium Alloy ZM21 by Surface Modification 375
A. Witecka, A. Yamamoto, and W. Swieszkowski
Cytocompatibility of Mg Alloys and the Effect of Cells on Their Degradation in Biological Environment 381
A. Yamamoto and Y. Kohyamda
Alloy Design
In–Situ Neutron Diffraction Study of Aging in Alloy ZK60A 389
S. Agnew, C. Calhoun, and B. Clausen
Development of a High Strength Ductile Wrought Mg–Zn Based Alloy 395
L. Ma, T. Sasaki, T. Nakata, T. Ohkubo, K. Hono, and S. Kamado
Significant Precipitation Strengthening in Extruded Mg–Sn–Zn Alloys 401
T. Sasaki, F. Elsayed, T. Nakata, S. Kamado, T. Ohkubo, and K. Hono
Al and Zn Impurity Diffusion in Binary and Ternary Magnesium Solid–Solutions 407
C. Kammerer, N. Kulkarni, R. Warmack, and Y. Sohn
Formation and Evolution of Intermetallic Phases in the Mg–Nd–Zn–Zr System 413
K. Peng, J. Zhang, Z. Zhang, and Q. Li
Light–Metal Matrix (Nano)–Composites
Microstructure–Property Relationships I
An Insight into Processing and Characteristics of Magnesium Based Composites 423
M. Gupta and W. Wong
Hot Extruded Carbon Nanotube Reinforced Magnesium Matrix Composites and Its Microstructure, Mechanical and Corrosion Properties 429
H. Mindivan, A. Efe, and E. Kayali
Hardening and Softening Processes in AJ51 Magnesium Alloy Reinforced with Short Saffil Fibres 435
Z. Trojanova, G. Farkas, K. Máthis, and P. Lukac
Microstructure–Property Relationships II: Modeling and Advanced Characterization
Fabrication and Tensile Properties of Al2O3 Particle and Fibre Hybrid Magnesium (AM60)–Based Composites 443
X. Zhang, Q. Zhang, H. Hu, and X. Nie
Enhancing Tensile and Compressive Strength of AZ41 Magnesium Alloy by Adding Nano–Sized Al2O3 449
M. Alam and A. Hamouda
Phase–Field Modeling of Solidification in Light–Metal Matrix Nanocomposites 455
T. Pusztai, L. Rátkai, A. Szállás, and L. Granasy
Advanced Characterization of Metal Matrix Nano–Composites 461
M. Maher and L. Williams
Emerging Processes
Achieving Uniform Distribution and Dispersion of a High Percentage Nanoparticles in Mg18Sn Matrix by Solidification Processing 467
L. Chen, J. Peng, J. Xu, H. Choi, and X. Li
Effect of Nano–Reinforcement on Properties of Cast Mg–Al Alloy AZ91 471
M. Mahmoud, I. El–Mahallawi, and R. Rashad
In–Situ Synthesis and Novel Additions
Ceramic Dispersions in Metal Castings Created by Direct Injection of a Liquid Organic Precursor into the Melt 479
R. Sudarshan
Magnesium Technology 2013
Addendum
Corrosion and Adhesion Properties of Cerium–Based Conversion Coatings on Magnesium Alloys 487
S. Maddela and M. O′Keefe
Corrosion of Ultrasonic Spot Weldbonds of Magnesium to Steel 491
T. Pan, Z. Feng, M. Santella, and J. Chen
Friction Stir Back Extrusion of Mg AZ31B–F: A Preliminary Investigation 497
J. Milner and F. Abu–Farha
Impurity Diffusion Coefficients of Al and Zn in Mg Determined from Solid–to–Solid Diffusion Couples 505
C. Kammerer, N. Kulkarni, R. Warmack, K. Perry, I. Belova, G. Murch, and Y. Sohn
Microstructure Evolution and Mechanical Behavior of Mg–10Gd–3Y–0.4Zr Alloy Processed by ECAP at High Temperature 511
Y. Zhou, D. Li, X. Zeng, Y. Wu, and W. Ding
The USAMP Magnesium Front End Research and Development Project Results of the Magnesium "Demonstration" Structure 517
J. Forsmark, M. Li, X. Su, D. Wagner, J. Zindel, A. Luo, J. Quinn, R. Verma, Y. Wang, S. Logan, S. Bilkhu, and R. McCune
Author Index 525
Subject Index 529
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