ISBN-13: 9783319565071 / Angielski / Twarda / 2017 / 253 str.
ISBN-13: 9783319565071 / Angielski / Twarda / 2017 / 253 str.
This book focuses on the application of classical combustion theory to ignition and flame propagation in solid-solid and gas-solid systems.
Preface………………………………………………………………………………………1
Acknowledgements…………………………………………………………………………7
Contents……………………………………………………………………………………..7
Introduction…………………………………………………………………………………9
References………………………………………………………………………………….23Chapter I. The theory of a local ignition…………………………………………………..28
§1. On the theory of a local thermal explosion…………………………………………..28
§2. Non-stationary ignition of a hot spot…………………………………………………34
§3. Initiation of a hydrogen-air flame with a hot spot.Verification of the theory…..40Conclusions to Chapter I…………………………………………………………………54
References………………………………………………………………………………..55
Chapter II. The wave theory of ignition…………………………………………………...57
§1. Ignition of the condensed substances with heat losses from the side surface………58
§2. Ignition of a condensed substance with a constant heat flux released in two competing
exothermic reactions…………………………………………………………………….67§3. The features of ignition of the condensed systems interacting through a layer of a refractory
product with an energy flux ……………………………………………………………77
§4. Regularities of ignition of the condensed systems with a heated surface according to theparabolic law of chemical interaction…………………………………………………..85
§5. Regularities of ignition of porous bodies under conditions of a counter non-stationary
filtration of gas…………………………………………………………………………..96
§6. Ignition of porous substances with the filterable gas. Cocurrent non-stationary
filtration…………………………………………………………………………………113
Conclusions to Chapter II………………………………………………………………….128
References…………………………………………………………………………………130
Chapter III. The convective-conductive theory of combustion of condensed
substances………………………………………………………………………………….133
§1. Convective combustion of “gasless” systems……………………………………..…..134§2. Convective heat and mass transfer in the processes of "gasless" combustion………...148
§3. The features of combustion of the mixes Ti+0.5C and Ti+C of bulk density in a cocurrent flow of inert gas………………………………………………………………………………….161
§4. Influence of humidity on the features of combustion of powder and granulated Ti+0.5C mixes………………………………………………………………………………………..171§5. Dependence of combustion velocity on the sample size in nonactivated and mechanically activated Ni +Al systems…………………………………………………………………...178
§6. Combustion of cylindrical Ti + 0.5C compacts: influence of mechanical activation,
thermovacuum processing, and ambient pressure…………………………………………..184
References…………………………………………………………………………………..188Conclusions to Chapter III…………………………………………………………………..193
Chapter 4. Theory of ignition of gas suspensions…………………………………………...194
§1. Analytical method of calculation of critical conditions of a local ignition
of gas suspensions of solid particles……………………………………………………..196
§2. Analysis of critical conditions of ignition of gas suspension with a heated body at pulse
energy supply……………………………………………………………………………205
§3. Mathematical modeling of the process of ignition of gas suspension of solid particles in a mix oxidizer - combustible gas (a local ignition)……………………………………………221
§4. Thermal ignition of hybrid gas suspensions in the presence of natural gas and chemically active additives…………………………………………………………….…………………233
References………………………………………………………………………………239
Conclusions to Chapter IV……………………………………………………………………242Chapter V. Ignition, combustion and passivation of nanopowders…………………………..243
§1. Ignition of pyrophoric powders: An entry-level model……………………………………247
§2. Temporal characteristics of ignition and combustion of iron nanoparticles in the air……254§3. Synthesis and characterization of passivated iron nanoparticles…………………………..263
§4. Passivation of iron nanoparticles at subzero temperatures…………………………………268
Conclusions to Chapter V………………………………………………………………………276
References………………………………………………………………………………………277Conclusions……………………………………………………………………………………..282
Professor Rubtsov (Institute of Structural Macrokinetics and Material Science Russian Academy of Sciences) works in the areas of experimental chemical kinetics, branching chain processes, detonation; vibronically excited particles as intermediates of complicated chain reactions; numerical simulation of combustion processes, protecting of metallization layers in VLSI; tautomeric equilibriums; solid combustion, nanoparticles combustion. He has published two other books with Springer: The Modes of Gaseous Combustion (Heat and Mass Transfer, 2016) and Key Factors of Combustion, From Kinetics to Gas Dynamics (Springer Aerospace Technology, 2017).
This book focuses on the application of classical combustion theory to ignition and flame propagation in solid-solid and gas-solid systems. It presents experimental investigations in the areas of local ignition, filtration combustion, self-propagating high temperature synthesis and nanopowders protection. The authors highlight analytical formulas used in different areas of combustion in solids and propose an approach based on classical combustion theory. The book attempts to analyze the basic approaches to understanding of solid-solid and solid - gas combustion presented in contemporary literature in a unified approach based on classical combustion theory.
1997-2024 DolnySlask.com Agencja Internetowa