Handbook of Benzoxazine Resins

ISBN-13: 9780444638441 / Angielski / Miękka / 2016 / 712 str.

Hatsuo Ishida; Tarek Agag

Opis

This handbook provides a wide overview of the field, fundamental understanding of the synthetic methods and structure/property correlation, as well as studies related to applications in a wide range of subjects. The handbook also provides ¹H and ¹³C NMR spectra, FTIR spectra, DSC and TGA thermograms to aid in research activities. Additional tables on key NMR and FTIR frequencies unique to benzoxazine, heat of polymerization, Tg, and char yield will greatly aid in the choice of proper benzoxazine for a specific application.

• Provides thorough coverage of the chemistry and applications of benzoxazine resins with an evidence-based approach to enable chemists, engineers and material scientists to evaluate effectiveness
• Features spectra, which allow researchers to compare results, avoid repetition and save time as well as tables on key NMR frequency, IR frequency, heat of polymerization, of many benzoxazine resins to aid them in selection of materials
• Written by the foremost experts in the field

Spis treści

Preface

Part I. Introduction
1. Overview and historical background of polybenzoxazine research
H. Ishida

Part II. Physical and Chemical Properties of Benzoxazine Resins
2. Synthesis of benzoxazines in solutions and melt
H. Ishida, and Jin-Ping Liu
3. Molecular modeling
Yi Gu, and Ming Li
4. Mono-substituted phenol-based benzoxazines : Inevitable dimerization via self-termination and its metal complexation
S. Chirachanchai, S. Phongtamrug, A. Laobuthee, and K. Tashiro
5. Using molecular simulation to predict the physical and mechanical properties of polybenzoxazines
I. Hamerton, B.J. Howlin, A.L. Mitchell, S.A.Hall, and L. McNamara
6. Chemorheology of benzoxazine-based resins
S. Rimdusit, C. Jubsilp, P. Kunopast, and W. Bangsen
7. Polymerization kinetics
C. Jubsilp, and S. Rimdusit
8. Electrochemical polymerization of benzoxazines
Wei Chen
9. Light Induced Reactions of Benzoxazines
M.At. Tasdelen, B. Kiskan, B. Gacal, F. Kasapoglu, L. Cianga, and Y. Yagci
10. Effect of Neighboring Groups on Enhancing Benzoxazine Autocatalytic Polymerization
M. Baqar, T. Agag, S. Qutubuddin, and H. Ishida
11. Catalytic Opening of Lateral Benzoxazine Rings by Thiols
I. Gorodisher, R.J. DeVoe, and R.J. Webb

Part III. Physical and Chemical Properties of Cross-linked Polybenzoxazines
12. Hydrogen bonding of polybenzoxazines
Ho-Dong Kim, and H. Ishida
13. Polybenzoxazines of Enhanced Thermal Properties: The Role of Additional Non-Benzoxazine Polymerizable Groups
T. Agag, S. Geiger, and H. Ishida
14. Thermal degradation mechanism of polybenzoxazines
J. Hacaloglu, T. Uyer, and H. Ishida

Part IV. Main-chain, Side-chain, Telechelic and Supramolecular Benzoxazine Architectures
15. Various approaches for main-chain type benzoxazine polymers
S. Alhassan, D. Schiraldi, T. Agag, S. Qutubuddin, and H. Ishida
16. Side and end chain benzoxazine functional polymers
B. Kiskan, and Y. Yagci
17. Supramolecular chemistry of benzoxazines: from simple, selective, effective, and efficient macrocyclization pathway to host-guest properties
S. Chirachanchai, S. Phongtamrug, and K. Tashiro
18. Main-chain type benzoxazine oligomers: A new concept for easily processable high performance polybenzoxazines
Jia Liu, T. Agag, and H. Ishida

Part V. Renewable Resources Based Polybenzoxazine Materials
19. Study of a cardanol-based benzoxazine as reactive diluent and toughening agent of conventional benzoxazines
P. Campaner, D. D'Amico, L. Longo, C. Stifani, A. Tarzia, and S. Tiburzio

Part VI. Polybenzoxazine Blends and Alloys
20. Polybenzoxazine/polyimide alloys
T. Takeichi, T. Kawauchi, and T. Agag
21. Polybenzoxazine/polyurethane alloys
H. Yeganeh
22. The Blends of a Silicon-containing Arylacetylene Resin and an Acetylene-Functional Benzoxazine
Farong Huang, Jianxiang Huang, Yu Gao, Yan Zhou, and Lei Du
23. Polybenzoxazine/polysiloxanes
T. Kawauchi, and T. Takeichi
24. Polybenzoxazine/bisoxazolines
H. Kimura, K. Ohtsuka, and A. Matsumoto

Part VII. Morphological Control of Polybenzoxazines
25. Morphology and properties of polybenzoxazine Blends
Chongyin Zhang, Lei Wang, Rentong Yu, and Sixun Zheng
26. Porous materials from polybenzoxazine
T. Chaisuwan
27. Spherical polybenzoxazine resin
Xinsheng Zheng, Yang Xue, Youmiao Xu, and Qianquan Chang

Part VIII. Polybenzoxazine Composites, Hybrid Materials and Nanocomposites
28. Polybenzoxazine /fiber composites
Yi Gu, and Qi-chao Ran
29. Polybenzoxazine-clay nanocomposites
T. Agag, and A. Akelah
30. Polybenzoxazine-POSS nanocomposites
Riwei Xu, Lei Wang, and Dingsheng Yu
31. Polybenzoxazine-CNT nanocomposites
Riwei Xu, Pengli Zhang, Jing Wang, and Dingsheng Yu

Part IX. Polybenzoxazine Applications and Potential Applications
32. Polybenzoxazines with enhanced flame retardancy
V. Cadiz, J. C. Ronda, G. Lligadas, M. Galia
33. Surface properties of polybenzoxazines
Chih-Feng Wang, Feng-Chih Chang, and Shiao-Wei Kuo
34. Advanced Benzoxazine Chemistries Provide Improved Performance in Broad Range of Applications
R. Tietze, and M. Chaudhari
35. Benzoxazines for Industrial Applications: Comparison with other Resins, Formulation & Toughening Know-how and Water-based Dispersion Technology
C. Sawaryn, S. Kreiling, R. Schoenfeld, K. Landfester, and A. Taden
36. Polybenzoxazines for increased dielectric constant
H. Manuspia, and H. Ishida
37. Preparation of Polybenzoxazine- Ni- Zn Ferrite nanocomposites and their magnetic property
N.N. Ghosh, and A.B. Rajput

Part X. Material Properties and Spectra
38. 1H NMR spectra of benzoxazine resins
39. FTIR spectra of benzoxazine resins
40. Raman spectra of benzoxazine resins
41. DSC thermograms of benzoxazine resins
42. TGA thermograms of benzoxazine resins
43. Dynamic mechanical spectra of benzoxazine resins