Electronic and Photoelectron Spectroscopy: Fundamentals and Case Studies

ISBN-13: 9780521817370 / Angielski / Twarda / 2005 / 302 str.

Andrew Ellis; Miklos Feher; Timothy Wright

Opis

Electronic and photoelectron spectroscopy provides extraordinarily detailed information on the properties of molecules. This book presents the basic principles and experimental techniques employed in electronic and photoelectron spectroscopy. A major feature is the extensive use of case studies to illustrate how spectra are assigned and how information can be extracted. The text is intended for advanced undergraduate and graduate students studying courses in spectroscopy.

Recenzje

Review of the hardback: 'This book is not only a useful book for a reasonable price, it is a very good book for graduate students in physical chemistry and all those who want to be introduced in modern spectroscopic techniques, and the results which may be obtained by these techniques. This book is a very helpful introduction into modern spectroscopy which guides the reader properly from the basic concepts to advanced principles. The book can be recommended not only for graduate students but also for all those who are engaging in teaching spectroscopy.' Zeitschrift für Physikalische Chemie

Spis treści

Preface; List of journal abbreviations; Part I. Foundations of Electronic and Photoelectron Spectroscopy: 1 Introduction; 2. Electronic structure; 3. Angular momentum in spectroscopy; 4. Classification of electronic states; 5. Molecular vibrations; 6. Molecular rotations; 7. Transition probabilities; Part II. Experimental Techniques: 8. The sample; 9. Broadening of spectroscopic lines; 10. Lasers; 11. Optical spectroscopy; 12. Photoelectron spectroscopy; Part III. Case Studies: 13. Ultraviolet photoelectron spectrum of CO; 14. Photoelectron spectra of CO2, OCS, and CS2 in a molecular beam; 15. Photoelectron spectrum of NO2−; 16. Laser-induced fluorescence spectroscopy of C3: rotational structure in the 300 nm system; 17. Photoionization spectrum of diphenylamine: an unusual illustration of the Franck–Condon principle; 18. Vibrational structure in the electronic spectrum of 1,4-benzodioxan: assignment of low frequency modes; 19. Vibrationally resolved ultraviolet spectroscopy of propynal; 20. Rotationally resolved laser excitation spectrum of propynal; 21. ZEKE spectroscopy of Al(H2O) and Al(D2O); 22. Rotationally resolved electronic spectroscopy of the NO free radical; 23. Vibrationally resolved spectroscopy of Mg+–rare gas complexes; 24. Rotationally resolved spectroscopy of Mg+–rare gas complexes; 25. Vibronic coupling in benzene; 26. REMPI spectroscopy of chlorobenzene; 27. Spectroscopy of the chlorobenzene cation; 28. Cavity ringdown spectroscopy of the a1∆←X3∑g− transition in O2; Appendices; Index.