Chiral Reactions in Heterogeneous Catalysis

ISBN-13: 9780306451102 / Angielski / Twarda / 1995 / 212 str.

Georges Jannes; V. DuBois; G. Jannes

Opis

Twenty papers investigate heterogeneous catalysis as the most desireable but still experimental and controversial method of preparing pure chiral compounds. Among the topics are the potential market for pure chiral compounds, enantio-differentiating hydrogenation of simple alkanones with an asymmetr

Spis treści

The Place of Heterogeneous Catalysis in the Chirality Field: Commercial Outlook for Chirality: Quo Vadis? (E. Polastro). Strategies for Asymmetric Synthesis: What Is the Role of Heterogeneous Catalysis? (L. Ghosez). Homogeneous Enantioselective Catalysis (H. Brunner). Hydrogenation Systems: Toward a Better Understanding: Enantiodifferentiating Hydrogenation of Simple Alkanones with Asymmetrically Modified Heterogeneous Catalyst (T. Osawa et al.). Enantiodifferentiating Hydrogenation of 2Butanone: Distinction between CH 3 and C 2 H 5 with a Modified Nickel Catalyst (T. Harada, T. Osawa). Asymmetric Hydrogenation of Ethyl Pyruvate Using Ptcontaining Zeolites Modified with ()Cinchonidine (W. Reschetilowski et al.). Hydrogenation Systems: Broadening the Scope: Enantio and Diastereoselective Reduction of Disubstituted Aromatics (K. Nasar et al.). Heterogeneous Asymmetric Catalysis with C 2 Symmetric Aminemodified Rhodium/Silica (P. Gamez). More Advanced Reactions: Chiral Dioxomolybdenum Complexes Anchored to Modified USYZeolites: Application to Selective Epoxidation of Olefins (A. Corma et al.). Effect of Sulfoxide Loading on the Selectivity and Activity of Zeolite Y for Dehydration Reactions (D. Bethell et al.). 11 additional articles. Index.