Catalysis of Organic Reactions: Twenty-second Conference

ISBN-13: 9780367386030 / Angielski / Miękka / 2019 / 548 str.

Michael L. Prunier

Opis

Based on findings gathered at the 22nd Conference on Catalysis of Organic Relations, this peer-reviewed volume covers the general area of catalyzed synthesis with particular emphasis on the production of organic chemicals. Using an applied rather than theoretical approach, the book’s dominant theme is the traditionally practiced area of heterogeneous catalysis. The contributors explore hydrogenation, hydrogenolysis, C-C coupling, and amination and oxidation, including the precious metal, supported base metal, sponge metal, Raney process, and homogeneous catalyst types. They also discuss end uses of these products, including industrial petrochemicals, fine chemicals, and pharma intermediates.

Spis treści

New Chemistry, Including Pulp Bleaching Processes, of the Golden-Aged, Water-Soluble Compound, Tris(hydroxymethyl) phosphine. Design and Serendipity in the Discovery and Development of Homogeneous Catalysts for Organic Synthesis. Asymmetric Hydrogenation of an Amino Acid Intermediate in the Synthesis of Complex Drug Targets: From Kinetic Modeling to Process Development. Process Intensification. Continuous Two-Phase Catalytic Reactions in a Table-Top Centrifugal Contact Separator. Application of Scavengers for the Removal of Palladium in Small Lot Manufacturing. Large-Scale Synthesis of Thienobenzazepine Derivatives Using Two Efficient Metal Catalyzed Processes Telescoped: Nitro Reduction and Intramolecular Aminocarbonylation. Manufacture and Application of Asymmetric Hydrogenation Catalysts. Hydrogenation of Nitro-Substituted Acetophenones. Tuning Selectivity through the Support in the Hydrogenation of Citral over Copper Catalysts. Improved Activity of Catalysts for the Production of Hydroxylamine. A .Trans-Effect. in Carbon Double-Bond Hydrogenation. Detailed Kinetic Analysis Reveals the True Reaction Path: Catalytic Hydrogenation, Hydrolysis and Isomerization of Lactose. Hydrogenation of a,ß-Unsaturated Aldehydes over Ir Catalysts Supported on Monolayers of Ti-Si and Nb-Si. 4,6-Diamino Resorcinol by Hydrogenation, a Case Study. Novel Hydrogenolysis Route to Perfluoroalkyl Ethane Thiols. New Insight into the Electrocatalytic Hydrogenation of Model Unsaturated Organic Compounds. Catalytic Reductive Alkylation of Aromatic and Alkyl Amines and Diamines over Sulfided and Unsulfided Platinum Group Metals. Catalytic Synthesis of N,N-Dialkylglucamines. Simple Catalytic Synthesis of N,N.-Dialkyl-N,N.-di(1-deoxyglucityl) ethylenediamines, Sugar-Based Gemini Surfactants. Anchored Wilkinson.s Catalyst: Comparison with the Homogeneous Catalyst and Supported Rhodium with Respect to Reaction Selectivity. Synthesis of New Ligands for the Preparation of Combined Homogeneous and

O autorze

Michael L. Prunier