Electronic Properties of Fullerenes: Proceedings of the International Winterschool on Electronic Properties of Novel Materials, Kirchberg, Tirol, March 6–13, 1993

ISBN-13: 9783642850516 / Angielski / Miękka / 2012 / 436 str.

Hans Kuzmany;Jorg Fink;Michael Mehring

Opis

Electronic Properties of Fullerenes and other Novel Materials gives an overview of the state-of-the-art research. It presents most recent results on preparation, experimental analysis by electron spectroscopy, infrared and Raman spectroscopy, luminescence, and nonlinear optical, as well as possible technological applications. Emphasis is also placed on the superconducting properties of Fullerenes. The introductory and advanced contributions provide a good survey of the current status of this rapidly developing field.

Spis treści

The Birth of C60: Buckminsterfullerene.- I Chemistry and Sample Preparation.- Fullerene Intercalation Compounds.- Chemical and Structural Aspects of the Interaction Between C60 and Molecular Oxygen.- A New Apparatus for Fullerene Production.- Implantation into Fullerites.- Voltammetric Studies on Fullerenes C60 and C70 in Low-Polarity Solvents.- Buried K-Fullerides by Ion Implantation.- C60-Fullerene in Water Solution, B3;-Cyclodextrin Complex and Cluster of C60: An NMR and a Photophysical Study.- Pulse Radiolytic Redox and Alkylation Studies on C60.- Photoionization Dynamics of C60.- Application of Fullerenes as Sensor Materials.- Generation of Graphitic Onions.- II Electronic Structure and Electron Spectroscopy.- Electronic Properties of Fullerenes in the Molecular and Solid Phases: A Brief Introductory Course to Theoretical Approaches.- Experimental Investigation of the Electronic Structure of Gas-Phase and Solid C60.- Low-Energy Electron Diffraction and High-Resolution Electron Energy-Loss Spectroscopy of Heteroepitaxial C60 Thin Films on GeS(001).- Electron Energy-Loss Studies on Rb-and Ca-Doped Fullerenes.- Electron Energy-Loss Spectroscopy of Free Fullerenes.- High-Resolution Photoemission Studies of A3C60 (A = K, Rb).- Electronic Structure of Alkaline-Earth Fullendes.- Jahn-Teller Distorted Excited States of C60.- The C60Molecule with the Step-Potential Model.- III Structure and Structural Phase Transitions.- Structure and Dynamics of C60 and C70.- K-C60- Growth Structures, Phase Formation, and Electronic Properties.- Structure and Lattice Dynamics of C70 Single Crystals.- Inelastic Neutron Scattering Study of the External Vibrations in C60.- Is K3C60 a Line Phase?.- Structural and Morphological Characterization of Fullerite Crystals Prepared from the Vapor Phase.- Low-Frequency Elastic Response in Single-Crystal C60.- Electron Microscopy of C60 and C70 Fullerites.- Orientational Order and Electron Density of C60 at Room Temperature Studied by Combined Neutron and X-Ray Diffraction on Single Crystals.- Orientational Glass Transition in Solid C60.- Orientational Ordering and Molecular Structure in Solid C60.- Molecular Dynamics Calculations on C60-Based Crystals.- Orientational Order in A3C60: Effects on Valence Bands and Infrared Optical Spectra.- Optical and SEM Studies of Morphology in C60 Films.- Characterization of a Pure C60 Powder Using Transmission Electron Microscopy.- Surface Imaging by Scanning Tunneling Microscopy of C60/70 Thin Films on Au(111) with Different C60/C70 Ratios.- Low-Temperature Scanning Tunneling Microscopy Study of C60 Fullerite.- Layer Disorder in C60-Ether Clathrates.- IV Infrared and Raman Spectroscopy, Luminescence, Transient Optics, and NLO.- Vibrational Spectroscopic Studies of Solid C60 Films.- Crystal Field Effects and Electronic Excitations in Single-Crystal C60.- Stability of Single-Crystal and Thin-Film Raman Spectra in C60.- Resonant Raman Scattering of the Normal and Superconducting State of A3C60 Films (A = Rb,K).- Raman Scattering and Lattice Dynamics of Fullendes M6C60 (M = K, Rb, Cs).- Stability of the Fullende Phase K1C60 as Observed from Raman Spectroscopy.- Raman Spectra of 13C-Substituted and Li-Intercalated Fullerenes.- Charge Transfer and Electron-Vibrational Mode-Coupling in Alkali-Metal-Doped C60.- Fullerene-Doped Conducting Polymers: Effects of Enhanced Photoconductivity and Quenched Photoluminescence.- Femtosecond Time-Resolved Optical Studies of Photoexcited States in C60.- Broadband Electroluminescence in Fullerene Crystals.- Nonlinear Phenomena in the Highly Excited State of C60.- Linear and Nonlinear Optical Properties of Fullerenes and Some Metal Derivatives.- Optical Properties of C60-Diethyl Ether Clathrate Single Crystals.- Optical Properties of Some New Fulleroids and Fullerene Polymers.- V Magnetic Resonance and Magnetic Ordering.- 13C Nuclear Relaxation in the Normal State of the K3C60 Superconductor.- Is the13C Nuclear Spin-Lattice Relaxation in A3C60 (A = Rb, K) Unconventional?.- NMR Investigation of K3C60 Under Pressure.- NMR on Alkali-Doped C60.- EPR and Overhauser Shift on [P¦±C60¯ and KxC60.- NMR Studies of Fullerene C60-Based Compounds.- QENS and NMR Investigation of Reorientational Dynamics in C61H2.- NMR Study of Orientational Ordering in C60 and the Magnetic Transition in TDAE-C60.- The Quest for New Magnetic Fullerene Material.- Pulsed EPR on the Photoexcited Triplet State of C60.- Electron Transfer from End-Capped Quaterthiophene to Photoexcited C60: A Pulsed EPR Investigation.- VI Electrical Transport and Superconductivity.- Transport Measurements of the Normal State and Superconducting Properties of Fullende Superconductors.- Magnetic Investigations of Superconducting Fullerenes.- The Electrodynamic Response in Superconducting Fullerenes.- Pairing on Small Clusters in the Peierls-Hubbard Model: Implications for C60.- Broadening and Anomalous Infrared Activity of the Hg-Derived Phonons in the Metallic Fullendes.- Langmuir-Blodgett Films of C60: Structure of Pure Films and Their Superconductivity After Exposure to Potassium Vapor.- Steady-State Photoconductivity of Fullerene Films.- Charge Transient Spectroscopy of Fullerites.- Characterisation of Fullerene Schottky Diodes.- Index of Contributors.