2-Oxoiminium Promoted Oxidative Cross Coupling Reactions

ISBN-13: 9783330858275 / Angielski / Miękka / 2017 / 228 str.

Qazi Naveed Ahmed

Opis

Given the attractive ability of 2-oxoaldehyde/ 2-oxoiminium ions to functionalize molecules directly at ostensibly unreactive positions, the reactivity of aldehydic group/ iminium ions having -CH2 group replaced by C=O is explored. Background studies on 2-oxo-driven unconventional reactions and the ability of 2-oxoiminium cations to promote reactions via an iminium-catalyzed or iminium-equivalent pathway are apparently unavailable. At this junction, we further envisaged that difference in activation of 2-oxoaldehydes and 2-oxoiminium cations lead us to develop new directions in 2-oxo driven novel chemistry

O autorze

C/O: Medicinal Chemistry Division, CSIR-Indian Institute of Integrative Medicine (CSIR), Canal Road, Jammu-180001, J&K, India.Senior Scientist, Medicinal Chemistry Division, CSIR-Indian Institute of Integrative Medicine