This book constitutes the refereed proceedings of the 14th International Conference on Verified Software. Theories, Tools and Experiments, VSTTE 2022 held in Trento, Italy, during October 17–18, 2022.The 9 papers presented in this volume were carefully reviewed and selected from 20 submissions. The papers describe software verification efforts that involve collaboration, theory unification, tool integration, and formalized domain knowledge as well as novel experiments and case studies evaluating verification techniques and technologies.