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Catalytic processes are highly essential for the sustainable development of organic mimics and thus symbolize the more economical impact. Therefore, study of these methodologies is of immense interest. To develop new chemistry, there is very much need of designing and synthesizing unexisting catalysts with various substituents for effective methodologies. As discussed above, metal-NHC complexes (palladium and copper-NHCs) are novel class of universal nucleophilic complexes capable of promoting different organic modifications. Recently, these have come into light as most successful class of...