The Chemistry of Organolithium Compounds

ISBN-13: 9780470843390 / Angielski / Twarda / 2004 / 1400 str.

Zvi Rappoport; Ilan Marek; Zvi Rappoport

Opis

This is the first volume in the series to concentrate on organo-lithium compounds - the sub series "The chemistry of the metal-carbon bond" (5 vol) treated organometallics in general. It deals with theoretical/physical/computational apsects, as well as major spectroscopies, such as MS, NMR, IR/UV etc and both biological and industrial applications.

• The core of the volume is the synthetic chapters with lots of examples for modern synthetic approaches
• Written by key researchers in the field
• An invaluable reference source to organic chemists working in academia and industry
• Features important reagents in organic synthesis

Spis treści

1. Theoretical studies in organolithium chemistry (Eluvathingal D. Jemmis and G. Gopakumar).

2. Lead structures in lithium organic chemistry (Thomas Stey and Dietmar Stalke).

3. Thermochemistry of organolithium compounds (Suzanne W. Slayden and Joel F. Liebman).

4. Solid state NMR spectroscopy in organolithium chemistry (Dan Johnels and Harald G¨unther).

5. Gas phase chemistry of organolithium compounds (Chagit Denekamp).

6. Vibrational spectroscopy of organolithium compounds (I. Pavel, W. Kiefer and D. Stalke).

7. Effects of structural variation on organolithium compounds (Marvin Charton).

8. Analytical aspects of organolithium compounds (Jacob Zabicky).

9. The preparation of organolithium reagents and intermediates (Frederic Leroux, Manfred Schlosser, Elinor Zohar and Ilan Marek).

10. Directed metallation of aromatic compounds (Jonathan Clayden).

11. Arene–catalyzed lithiation (Miguel Yus).

12. Rearrangements of organolithium compounds (Katsuhiko Tomooka).

13. Lithium carbenoids (Manfred Braun).

14. Addition of organolithium reagents to double bonds (Hiroshi Yamataka, K. Yamada and K. Tomioka).

15. Polylithium organic compounds: Syntheses and selected molecular structures (Carsten Strohmann and Daniel Schildbach).

16. –Amino–organolithium compounds (Robert E. Gawley and Iain Coldham).

17. Asymmetric deprotonation with alkyllithium ( )–sparteine (Dieter Hoppe and Guido Christoph).

18. Reactivity of oxiranes with organolithium reagents (Fabrice Chemla and Emmanuel Vrancken).

Author index.

Subject index.

Blurb

The Patai Series publishes comprehensive reviews on all aspects of specific functional groups. Each volume contains outstanding surveys on theoretical and computational aspects, NMR, MS, other spectroscopical methods and analytical chemistry, structural aspects, thermochemistry, photochemistry, synthetic approaches and strategies, synthetic uses and applications in chemical and pharmaceutical industries, biological, biochemical and environmental aspects.

To date, over 100 volumes have been published in the series.

Recently Published Titles

The chemistry of the Cyclopropyl Group (Volume 2)

The chemistry of the Hydrazo Azo and Azozy Groups (Volume 2, 2 parts)

The chemistry of Double–Bonded Functional Groups (Volume 3, 2 parts)

The chemistry of Organophosphorus Compounds (Volume 4)

The chemistry of Halides, Pseudo–Halides and Azides (Volume 2, 2 parts)

The chemistry of the Amino, Nitro and Nitroso Groups (2 volumes, 2 parts)

The chemistry of Dienes and Polyenes (2 volumes)

The chemistry of Organic Derivatives of Gold and Silver

The chemistry of Organic Silicon Compounds (2 volumes, 4 parts)

The chemistry of Organic Germanium, Tin and Lead Compounds (Volume 2, 2 parts)

The chemistry of Phenols (2 parts)

The chemistry of Organolithium Compounds (2 parts)

Forthcoming Titles

The chemistry of Cyclobutanes

The chemistry of Peroxides (Volume 2)

The Patai Series Online

Starting in 2003 the Patai Series will be available in electronic format on Wiley InterScience. All new titles will be published online and a growing list of older titles will be added every year. It is the ultimate goal that all titles published in the Patai Series will be available in electronic format.

For more information see the Patai Series Online website:

www.interscience.wiley.com/bookfinder.html