Nanocatalysis: Synthesis and Applications

ISBN-13: 9781118148860 / Angielski / Twarda / 2013 / 736 str.

Vivek Polshettiwar; Tewodros Asefa

Opis

Exhibiting both homogeneous and heterogeneous catalytic properties, nanocatalysts allow for rapid and selective chemical transformations, with the benefits of excellent product yield and ease of catalyst separation and recovery. This book reviews the catalytic performance and the synthesis and characterization of nanocatalysts, examining the current state of the art and pointing the way towards new avenues of research. Moreover, the authors discuss new and emerging applications of nanocatalysts and nanocatalysis, from pharmaceuticals to fine chemicals to renewable energy to biotransformations. Nanocatalysis features contributions from leading research groups around the world. These contributions reflect a thorough review of the current literature as well as the authors' first-hand experience designing and synthesizing nanocatalysts and developing new applications for them. The book's nineteen chapters offer a broad perspective, covering:

• Nanocatalysis for carbon-carbon and carbon-heteroatom coupling reactions
• Nanocatalysis for various organic transformations in fine chemical synthesis
• Nanocatalysis for oxidation, hydrogenation, and other related reactions
• Nanomaterial-based photocatalysis and biocatalysis
• Nanocatalysts to produce non-conventional energy such as hydrogen and biofuels
• Nanocatalysts and nano-biocatalysts in the chemical industry

Readers will also learn about the latest spectroscopic and microscopy tools used in advanced characterization methods that shed new light on nanocatalysts and nanocatalysis. Moreover, the authors offer expert advice to help readers develop strategies to improve catalytic performance. Summarizing and reviewing all the most important advances in nanocatalysis over the last two decades, this book explains the many advantages of nanocatalysts over conventional homogeneous and heterogeneous catalysts, providing the information and guidance needed for designing green, sustainable catalytic processes.

Spis treści

Foreword vii
Graham Hutchings

Preface ix

List of Contributors xiii

1 INTRODUCTION TO NANOCATALYSIS 1
Vivek Polshettiwar and Tewodros Asefa

2 NANOCATALYSTS FOR THE HECK COUPLING REACTIONS 11
T. Asefa, A. V. Biradar, S. Das, K. K. Sharma, and R. Silva

3 NANOCATALYSTS FOR THE SUZUKI COUPLING REACTIONS 51
Liane M. Rossi, Natalia J. S. Costa, Jones Limberger, and Adriano L. Monteiro

4 SONOGASHIRA REACTIONS USING NANOCATALYSTS 89
Rafael Chinchilla and Carmen N´ajera

5 NANOCATALYSTS FOR HIYAMA, STILLE, KUMADA, AND NEGISHI C C COUPLING REACTIONS 133
Abhinandan Banerjee and Robert W. J. Scott

6 ARYL CARBON HETEROATOM COUPLING REACTIONS USING NANOMETAL CATALYST 189
Brindaban C. Ranu, Debasree Saha, Debasish Kundu, and Nirmalya Mukherjee

7 NANOSTRUCTURED CATALYSTS FOR THE ALDOL, KNOEVENAGEL, AND HENRY REACTIONS 221
T. Asefa, A. V. Biradar, S. Das, and R. Silva

8 NANOCATALYSTS FOR REARRANGEMENT REACTIONS 251
Joaqu´ýn Garc´ýa–A´lvarez, Sergio E. Garc´ýa–Garrido, and Victorio Cadierno

9 OXIDATION OF ALCOHOLS USING NANOCATALYSTS 287
Takato Mitsudome and Kiyotomi Kaneda

10 TUNING THE MORPHOLOGY OF METAL OXIDES FOR CATALYTIC APPLICATIONS 333
Yong Li and Wenjie Shen

11 NANOCATALYSTS FOR HYDROGENATION REACTIONS 405
Radha Narayanan

12 HYDROGENOLYSIS REACTIONS USING NANOCATALYSTS 443
Aziz Fihri and Vivek Polshettiwar

13 NANOMATERIAL–BASED PHOTOCATALYSTS 469
Biswajit Mishra and Deepa Khushalani

14 NANOCATALYSTS FOR WATER SPLITTING 495
Xu Zong, Gaoqing Lu, and Lianzhou Wang

15 PROPERTIES OF NANOCATALYTIC MATERIALS FOR HYDROGEN PRODUCTION FROM RENEWABLE RESOURCES 561
Zhong He and Xianqin Wang

16 NANOCATALYSTS FOR BIOFUELS 595
Vitaliy Budarin, Peter S. Shuttleworth, Brigid Lanigan, and James H. Clark

17 NANOMATERIAL–BASED BIOCATALYST 615
Jin Hyung Lee, Soo Youn Lee, Zhi–Kang Xu, and Jeong Ho Chang

18 ROLE OF NANOCATALYSIS IN CHEMICAL INDUSTRY 643
Anirban Ghosh, K. S. Nagabhushana, Debabrata Rautaray, and Rajiv Kumar

19 NANOCATALYSIS: ACTIVATION OF SMALL MOLECULES AND CONVERSION INTO USEFUL FEEDSTOCK 679
Suresh Babu Kalidindi and Balaji R. Jagirdar

Index 713

O autorze

VIVEK POLSHETTIWAR, PhD, is Reader heading the Nanocatalysis Laboratory in the Department of Chemical Sciences at the Tata Institute of Fundamental Research. His research examines advanced nanomaterials, catalysis, and green chemistry.

TEWODROS ASEFA, PhD, is Associate Professor in the Department of Chemistry and Chemical Biology and the Department of Chemical and Biochemical Engineering at Rutgers University. Dr. Asefa is also Interim Director of the Rutgers Catalysis Research Center.

Blurb

Sets the stage for the development of new, environmentally friendly catalytic reactions

Exhibiting both homogeneous and heterogeneous catalytic properties, nanocatalysts allow for rapid and selective chemical transformations, with the benefits of excellent product yield and ease of catalyst separation and recovery. This book reviews the catalytic performance and the synthesis and characterization of nanocatalysts, examining the current state of the art and pointing the way towards new avenues of research. Moreover, the authors discuss new and emerging applications of nanocatalysts and nanocatalysis, from pharmaceuticals to fine chemicals to renewable energy to biotransformations.

Nanocatalysis features contributions from leading research groups around the world. These contributions reflect a thorough review of the current literature as well as the authors′ first–hand experience designing and synthesizing nanocatalysts and developing new applications for them. The book′s nineteen chapters offer a broad perspective, covering:

• Nanocatalysis for carbon–carbon and carbon–heteroatom coupling reactions
• Nanocatalysis for various organic transformations in fine chemical synthesis
• Nanocatalysis for oxidation, hydrogenation, and other related reactions
• Nanomaterial–based photocatalysis and biocatalysis
• Nanocatalysts to produce non–conventional energy such as hydrogen and biofuels
• Nanocatalysts and nano–biocatalysts in the chemical industry

Readers will also learn about the latest spectroscopic and microscopy tools used in advanced characterization methods that shed new light on nanocatalysts and nanocatalysis. Moreover, the authors offer expert advice to help readers develop strategies to improve catalytic performance.

Summarizing and reviewing all the most important advances in nanocatalysis over the last two decades, this book explains the many advantages of nanocatalysts over conventional homogeneous and heterogeneous catalysts, providing the information and guidance needed for designing green, sustainable catalytic processes.