Bioinorganic Chemistry OEC in Photo System-II » książka
Bioinorganic Chemistry OEC in Photo System-II
ISBN-13: 9783848449040 / Angielski / Miękka / 2012 / 52 str.
We report here the full description of a comprehensive synthetic methodology to isolate MnIIIMnIII, MnIIIMnIV, and MnIVMnIV dimers. The dimers Mn2III/III(mu-O)(-OAc)2(MeL*)2] ClO4]2.CH2Cl2 (1), Mn2III/IV(mu-O)2(mu-OAc)(MeL*)2] ClO4]2 (2) and Mn2IV/IV(mu-O)2(mu-OAc)(MeL*)2] ClO4]3.2H2O (3) have been isolated, and complex 1 and 2 have been structurally characterized. Complex 3 has been used as an oxidant of a range of substituted phenolic substrates.
We report here the full description of a comprehensive synthetic methodology to isolate MnIIIMnIII, MnIIIMnIV, and MnIVMnIV dimers. The dimers [Mn2III/III(mu-O)(-OAc)2(MeL*)2][ClO4]2.CH2Cl2 (1), [Mn2III/IV(mu-O)2(mu-OAc)(MeL*)2][ClO4]2 (2) and [Mn2IV/IV(mu-O)2(mu-OAc)(MeL*)2][ClO4]3.2H2O (3) have been isolated, and complex 1 and 2 have been structurally characterized. Complex 3 has been used as an oxidant of a range of substituted phenolic substrates.
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